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Research Group Jarl Ivar van der Vlugt

 

Contact:

J.I. (Jarl Ivar) van der Vlugt

dr.ir. Jarl Ivar van der Vlugt
Assistant Professor
Homogeneous, Supramolecular and Bio-Inspired Catalysis
Van 't Hoff Institute for Molecular Sciences
Faculty of Natural Sciences University of Amsterdam
P.O. Box 94720
1090 GS Amsterdam, the Netherlands
phone: +31 (0)20 525 6459
e-mail: j.i.vandervlugt@uva.nl

Biography:

Jarl Ivar van der Vlugt (1975) studied chemistry & chemical engineering at the Eindhoven University of Technology (TU/e) in the Netherlands, from late 1993 till early 1999. He then joined the newly established Homogeneous Catalysis group of prof. Dieter Vogt at the TU/e and in late 2003 also became the first member of the group to earn his PhD. degree. For the work described in his thesis, dealing with the design of novel, versatile ligand scaffolds and their application in the Rh-catalyzed hydroformylation, he was awarded the 2003-2004 Catalysis Prize of the Royal Dutch Chemistry Association (KNCV). After a short stay as a research fellow in Eindhoven, he switched gears (and continents) and moved to the University of Illinois at Urbana-Champaign (USA) in early 2004 to carry out postdoctoral research with prof. Tom Rauchfuss in the area of bioinorganic chemistry, working on small-molecule models for the Fe-only hydrogenase active site. Supported by an Alexander-von-Humboldt Fellowship he moved to the Georg-August-Universität Göttingen in Germany in late 2005 to join the research group of prof. Franc Meyer, where he developed new dinucleating bipyridyl functionalized pyrazolate ligands predestined for self-assembly. Mid 2006 he was awarded a VENI Innovation Grant by the Dutch Science Foundation (NWO) and he relocated to the TU/e at the beginning of 2007 to start his independent research (in the group of prof. Vogt) in the area of homogeneous catalysis and coordination chemistry, with a focus on N-H activation, hydroamination catalysts, non-innocent ligands and cooperative effects in catalysis. Late 2008 he moved to his present position as assistant professor in the Supramolecular and Homogeneous Catalysis group of prof. Joost Reek at the University of Amsterdam (UvA) in the Netherlands. He received a prestigious ERC Starting Grant for the period 2012-2017 and he currently heads a group of 4 PhD students; he is also committed as co-PI to several other projects (both PhD and PDF) within the research group. He is actively involved in teaching on both B.Sc. and M.Sc. levels, with emphasis on inorganic chemistry, organometallic chemistry, homogeneous catalysis and bioinorganic chemistry as well as supervising various laboratory courses. He is a member of the national HRSMC and NIOK Research Schools and the EU COST action “PhoSciNet”.

Various PhD positions:


Current Research Profile

Bioinspired Ligand Design and Homogeneous Catalysis

The group has a strong, experimental background in (in)organic synthesis, organometallic chemistry and homogeneous catalysis, mainly directed to ligand design and (asymmetric) hydrofunctionalization reactions. Current work deals with new ligand concepts and applications in e.g. encapsulated metal complexes (Chem. Commun. 2010; Inorg. Chem. 2010). A highlight (Angew. Chem. Int. Ed. 2010) and invited review (Chem. Soc. Rev. 2010) show our passion for novel concepts and catalytic reactivity.
The group is currently very active at the forefront of the new research field of cooperative catalysis with non-innocent ligands, with contributions focussed on the use of earth-bundant, benign first row transition metals with versatile ligand frameworks (minireview Eur. J. Inorg. Chem. 2012). We described the first example of hemilabile coordination and reactive chemistry with PNP-ligands to Cu (Inorg. Chem. 2008, 2009) and related chemistry with Ni (Dalton Trans. 2009), illustrating the groundbreaking potential for bioinspired cooperative catalysis with these sustainable metals, as well as practical applications with Pd(Organometallics 2009). The first class of tunable flexidentate ligands was recently developed (Organometallics 2011).Research on cooperative systems will open up a wide range of catalyticorganic transformations and is foreseen to have major impact on the utilization of renewable feedstocks and challenging small molecules. A recent review (Angew. Chem. Int. Ed. 2009) and invited contributions to themed issues (Dalton Trans. 2011); Inorg. Chim. Acta 2012) demonstrate our developing position in the area of cooperative ligand design and underscore our ambition to become a leading group in this field. We collaborate withspectroscopists and computational chemists to gain fundamental insight for these systems. Current interests include bioinspired small molecule activation, bioinorganic chemistry, ligand design, catalysis for green energy production and cooperative catalysts. Jarl Ivar van der Vlugt obtained several grants in recent years, including an ERC Starting Grant in 2011.


Publications

Publication List dr.ir. Jarl Ivar van der Vlugt

                                                                                                                       # citations

2016

81     Reversible redox chemistry and catalytic C(sp3)-H amination reactivity of a paramagnetic Pd complex bearing a redox-active o-aminophenol-derived NNO pincer ligand
D.L.J. Broere, N.P. van Leest, B. de Bruin, J.I. van der Vlugt*
Inorg. Chem. 2016, 55, doi: 10.1021/acs.inorgchem.6b01192.                            (-)

80     Arene C(sp2)-H metalation at NiII modeled with a reactive PONCPh ligand
L.S. Jongbloed, D. García-López, R. van Heck, M.A. Siegler, J.J. Carbo, J.I. van der Vlugt*
Inorg. Chem. 2016, 55, doi: 10.1021/acs.inorgchem.6b01162.                            (-)

79     Ligand-based mixed-valence in a triazole-bridged dinuclear palladium complex
D.L.J. Broere, R. Plessius, J. Tory, S. Demeshko, B. de Bruin, M.A. Siegler, F. Hartl, J.I. van der Vlugt*
Chem. Eur. J. 2016, 22, doi: 10.1002/chem.201601900.                                                 (-)

78     Dinuclear Au-complexes supported by a single ligand framework
V. Vreeken, D.L.J. Broere, A.C.H. Jans, M. Lankelma, J.N.H. Reek, M.A. Siegler, J.I. van der Vlugt*
Angew. Chem. Int. Ed. 2016, 55,doi: 10.1002/anie.201603938.                                     (-)

77     Versatile coordination of a reactive P,N-ligand toward boron, aluminum and gallium
M. Devillard, C. Alvarez Lamsfus, V. Vreeken, L. Maron, J.I. van der Vlugt*
Dalton Trans. 2016, 45, 10989-10998.                                                                (-)

76     Redox-active ligand mediated formation of an acyclic trinuclear ruthenium complex with bridging nitrido ligands
B. Bagh, D.L.J. Broere, M.A. Siegler, J.I. van der Vlugt*
Angew. Chem. Int. Ed. 2016, 55,8381-8385.                                                       (-)

75     Redox-chemistry of iminopyridyl ligands in Rh(I)- and Ir(I)-complexes
Z. Tang, C. Tejel, M. Lutz, J.I. van der Vlugt, B. de Bruin
Eur. J. Inorg. Chem. 2016, 963-974.                                                                    (-)
74     Metal-metal interactions in heterobimetallic complexes with dinucleating redox active ligands
D.L.J. Broere, D.K. Modder, E. Blokker, M.A. Siegler, J.I. van der Vlugt*
Angew. Chem. Int. Ed. 2016, 55,2406-2410.                                                      (-)

73     Base-free formic acid dehydrogenation via reversible cyclometalation (inside front cover)
L.S. Jongbloed, B. de Bruin, J.N.H. Reek, M. Lutz, J.I. van der Vlugt*
Catal. Sci. Technol. 2016, 6, 1320-1327.                                                                         (-)

72     Hydrogenation of CO2 to formic acid with iridiumIII(bisMETAMORPhos)(hydride): the role of a dormant fac-IrIII(trihydride) and an active trans-IrIII(dihydride) species
S. Oldenhof, J.I. van der Vlugt,* J.N.H. Reek*
Catal. Sci. Technol. 2016, 6, 404-408.                                                                 (1)

 

2015

71     Platinum(II) metallamacrocycles with a ditopic diphosphine ligand
A.E. Pascui, K. van Rees, D.W. Zant, D.L.J. Broere, M.A. Siegler, J.I. van der Vlugt*
Eur. J. Inorg. Chem. 2015, 5687-5693.                                                                 (-)

70     Rh-catalyzed conversion of carbenes into ketenes and ketene imines
Z. Tang, M. Lutz, J.I. van der Vlugt, B. de Bruin
Org. Chem. Front. 2015, 2, 1561-1577.                                                               (2)

69     Hydrogenation of carboxylic acids with a homogeneous cobalt catalyst
T.J. Korstanje, J.I. van der Vlugt, C.J. Elsevier, B. de Bruin
Science 2015, 350, 298-302.                                                                               (6)

68     Intermolecular C-H activation with an Ir-METAMORPhos piano-stool complex – Multiple reaction steps at a reactive ligand
S. Oldenhof, M. Lutz, J.I. van der Vlugt,* J.N.H. Reek*
Chem. Commun. 2015, 51, 15200-15203.                                                                         (2)
67     New avenues for ligand-mediated processes – Expanding metal reactivity by the use of redox-active catechol, o-aminophenol and o-phenylenediamine ligands
D.L.J. Broere, R. Plessius, J.I. van der Vlugt*
Chem. Soc. Rev. 2015, 44, 6886-6915.                                                              (20)

66     Dynamic ligand reactivity in a rhodium pincer complex (front cover)
Z. Tang, E. Otten, J.N.H. Reek, J.I. van der Vlugt,* B. de Bruin*
Chem. Eur. J. 2015, 21, 12683-12693.                                                                 (8)
         Hot Paper

65     Formation and site-selective reactivity of a nonsymmetric dinuclear iridium bisMETAMORPhos complex
S. Oldenhof, F.G. Terrade, M.Lutz, J.I. van der Vlugt,* J.N.H. Reek*
Organometallics 2015, 34, 3209-3215.                                                                (5)

64     Efficient C-H activation of arenes by a photoactivated NiII(azide) – Formation of a transient nickel nitrido complex
V. Vreeken, M. Lutz, B. de Bruin, J. N. H. Reek, M.A. Siegler, J.I. van der Vlugt*
Angew. Chem. Int. Ed. 2015, 54, 7055-7059.                                                       (3)

63     Facile synthesis and versatile reactivity of an unusual cyclometalated RhI pincer complex
L.S. Jongbloed, B. de Bruin, J.N.H. Reek, M. Lutz, J.I. van der Vlugt*
Chem. Eur. J. 2015, 21, 7297-7305.                                                                     (9)

62     Chiral wide bite angle diphosphine ligands: Synthesis, coordination chemistry and application in Pd-catalyzed allylic alkylation
C.F. Czauderna, A.G. Jarvis, F.J.L. Heutz, D.B. Cordes, A.M.Z. Slawin, J.I. van der Vlugt, P.C.J. Kamer
Organometallics 2015, 34, 1608-1618.                                                               (2)
61     Dinuclear palladium complexes with two ligand-centered radicals and a single bridging ligand: Subtle tuning of magnetic properties
D.L.J. Broere, S. Demeshko, B. de Bruin, E.A. Pidko, J.N.H. Reek, M. Lutz, M.A. Siegler, J.I. van der Vlugt*
Chem. Eur. J. 2015, 21, 5879-5886.                                                                     (8)

60     Platinum(II)-porphyrin as a sensitizer for visible light-driven water oxidation in neutral phosphate buffer solution
H.-C. Chen, D.G.H. Hetterscheid, R. Williams, J.I. van der Vlugt, J.N.H. Reek, A.M. Brouwer
Energy Environ. Sci. 2015, 8, 975-982.                                                                (9)

59     Formic acid dehydrogenation by Ir-bisMETAMORPhos complexes: Experimental and computational insight in the role of a cooperative ligand acting as H-bond acceptor
S. Oldenhof, M. Lutz, B. de Bruin, J.I. van der Vlugt, J.N.H. Reek
Chem. Sci. 2015, 6, 1027-1034.                                                                                     (13)

58     Redox-active ligand-induced homolytic bond activation
D.L.J. Broere, L.L. Metz, B. de Bruin, J.N.H. Reek, M.A. Siegler, J.I. van der Vlugt*
Angew. Chem. Int. Ed. 2015, 54, 1516-1520.                                                     (20)

57     Cobaloxime encapsulation in a photo-active metal-organic framework for light-driven H2 production
M. Nasalevich, R. Becker, E.V. Ramos-Fernandez, S. Castellanos, S.L. Veber, M.V. Fedin, F. Kapteijn, J.N.H. Reek,* J.I. van der Vlugt,* J. Gascon*
Energy Environ. Sci. 2015, 8, 364-375.                                                              (30)


2014

56     A well-defined bisMETAMORPhos PdI-PdI complex: Synthesis, structural characterization and reactivity
S. Oldenhof, M. Lutz, B. de Bruin, J.I. van der Vlugt, J.N.H. Reek
Organometallics 2014, 33, 7293-7298.                                                                (9)

55     Intramolecular redox-active ligand-to-substrate single electron transfer: Radical reactivity with a palladium(II) complex (front cover)
D.L.J. Broere, B. de Bruin, J.N.H. Reek, M. Lutz, S. Dechert, J.I. van der Vlugt*
J. Am. Chem. Soc. 2014, 136, 11574-11577.                                                     (28)
         JACS Spotlights highlight

54     An isolated ‘nitridyl-radical’ bridged RhN•Rh complex
Y. Gloaguen, C. Rebreyend, M. Lutz, P. Kumar, M.I. Huber, J.I. van der Vlugt, S. Schneider, B. de Bruin
Angew. Chem. Int. Ed. 2014, 53, 6814-6818.                                                     (21)

53     Synthesis, coordination chemistry and cooperative activation of H2 with ruthenium complexes of proton-responsive METAMORPhos ligands
F.G. Terrade, M. Lutz, J.I. van der Vlugt,* J.N.H. Reek*
Eur. J. Inorg. Chem. 2014, 1826-1835.                                                               (11)
invited articleissue ‘Advances in Phosphorus Chemistry’

52     Hybrid diphosphorus ligands in Rh catalyzed asymmetric hydroformylation
S.H. Chikkali,* J.I. van der Vlugt,* J.N.H. Reek*
Coord. Chem. Rev. 2014, 262, 1-15.                                                                   (27)

51     Synthesis and reactivity of chiral wide bite angle hybrid diphosphorus ligands
C.F. Czauderna, D.B. Cordes, A.M.Z. Slawin, C. Müller, J.I. van der Vlugt, D. Vogt, P.C.J. Kamer
Eur. J. Inorg. Chem. 2014, 1797-1810.                                                                 (7)

 

2013

50     Nitrogen centered ligand radical complexes: Classification, spectroscopic features, reactivity and catalytic applications
A.I. Olivos Suarez, V. Lyaskovskyy, J.N.H. Reek, J.I. van der Vlugt, B. de Bruin
Angew. Chem. Int. Ed. 2013, 52, 12510-12529.                                                 (44)

49     Reductive elimination at an orthometalated IrIII hydride bearing a tripodal tetraphosphorus ligand
Y. Gloaguen, L.M. Jongens, J.N.H. Reek, M. Lutz, B. de Bruin, J.I. van der Vlugt*
Organometallics 2013, 32, 4284-4291.                                                              (10)

48     Base-free production of H2 by dehydrogenation of formic acid using an iridium-bisMETAMORPhos complex
S. Oldenhof, B. de Bruin, M. Lutz, M.A. Siegler, F.W. Patureau, J.I. van der Vlugt, J.N.H. Reek
         Chem. Eur. J. 2013, 19, 11507-11511.                                                              (36)

47     Catalyst recycling via specific non-covalent adsorption on modified silicas
A.M. Kluwer, C. Simons, Q. Knijnenburg, J.I. van der Vlugt, B. de Bruin, J.N.H. Reek
Dalton Trans. 2013, 42, 3609-3616.                                                                     (6)

46     Reactivity of a mononuclear IrI species bearing a terminal phosphido fragment embedded in a triphosphorus ligand
Y. Gloaguen, W. Jacobs, B. de Bruin, M. Lutz, J.I. van der Vlugt*
Inorg. Chem. 2013, 52, 1682-1684.                                                                   (24)

45     Regioselective Pd-catalyzed hydroamination of substituted dienes
A. Perrier, M. Ferreira, J.N.H. Reek, J.I. van der Vlugt*
         Catal. Sci. Technol. 2013,3, 1375-1379.                                                                         (4)

44     A noble-metal free system for photocatalytic proton reduction 
B. van den Bosch, H.-C. Chen, J.I. van der Vlugt, A.M. Brouwer, J.N.H. Reek
ChemSusChem 2013, 6, 790-793.                                                                        (9)


2012

43     N-H bond activation by palladium(II) and copper(I) complexes featuring a cooperative bidentate PN-ligand (front cover)
         S.Y. de Boer, Y. Gloaguen, J.N.H. Reek, M. Lutz, J.I. van der Vlugt*
Dalton Trans. 2012, 41, 11276-11283.                                                               (26)

42     Highly selective asymmetric Rh-catalyzed hydroformylation of heterocyclic olefins
         S.H. Chikkali, R. Bellini, B. de Bruin, J.I. van der Vlugt, J.N.H. Reek
J. Am. Chem. Soc. 2012, 134, 6607-6616.                                                                      (42)

41     Supramolecular asymmetric catalysis
         R. Bellini, J.I. van der Vlugt, J.N.H. Reek
         Isr. J. Chem. 2012, 52, 613-629.                                                                         (18)

40     CuI click catalysis with cooperative noninnocent pyridylphosphine ligands
            S.Y. de Boer, Y. Gloaguen, M. Lutz, J.I. van der Vlugt*
Inorg. Chim. Acta 2012, 380, 336-342.                                                               (27)
invited articleissue ‘Inorganic Chemistry – the Next Generation’

39     First row transition metal cooperative catalysis (front cover)                              
            J.I. van der Vlugt*
Eur. J. Inorg. Chem. 2012, 363-375.                                                                  (145)
invited micro-reviewissue ‘Cooperative & Redox Noninnocent Ligands’
         top-3 most cited articles of 2011-2012 & top-10 most accessed articles 06/2013-12/2015

 

2011

38     Pincer ligands with an all-phosphorus donor set: Subtle differences between rhodium and palladium
            R.C. Bauer, Y. Gloaguen, M. Lutz, J.N.H. Reek, B. de Bruin, J.I. van der Vlugt*
         Dalton Trans. 2011, 40, 8822-8829.                                                                   (29)
invited articleissue ‘Pincers and other Hemilabile Ligands’

37     Dinuclear CuI thiolate complexes with a bridging noninnocent PNP-ligand
            J.I. van der Vlugt,* E.A. Pidko, R.C. Bauer, Y. Gloaguen, M.K. Rong, M. Lutz
Chem. Eur. J. 2011, 17, 3850-3854.                                                                   (36)

36     Ligands that store & release electrons during catalysis
            W.I. Dzik, J.I. van der Vlugt, J.N.H. Reek, B. de Bruin
Angew. Chem. Int. Ed. 2011, 50, 3356-3358.                                                     (97)

35     Tunable hemilabile ligands for adaptive late transition metal complexes
            R. Lindner, B. van den Bosch, M. Lutz, J.N.H. Reek, J.I. van der Vlugt*
Organometallics 2011, 30, 499-510.                                                                  (65)


2010

34     Versatile new C3-symmetric tripodal tetraphosphine ligands; Structural flexibility to stabilize CuI and RhI species and their reactivity
            J. Wassenaar, M.A. Siegler, A.L. Spek, B. de Bruin, J.N.H. Reek,* J.I. van der Vlugt*
Inorg. Chem. 2010, 49, 6495-6508.                                                                    (15)

33     Highly enantioselective hydroformylation of dihydrofurans catalyzed by hybrid phosphine-phosphonite rhodium complexes
            S.H. Chikkali, R. Bellini, G. Berthon-Gelloz, J.I. van der Vlugt, B. de Bruin, J.N.H. Reek
Chem. Commun. 2010, 46, 1244-1246.                                                               (36)

32     Advances in selective activation and application of ammonia in homogeneous catalysis
            J.I. van der Vlugt*
Chem. Soc. Rev. 2010, 39, 2302-2322.                                                              (85)
invited critical review

31     Boryl based pincer ligands: New avenues in boron chemistry
            J.I. van der Vlugt*
Angew. Chem. Int. Ed. 2010, 49, 252-255.                                                                     (41)
invited highlight

30     Activation of H2 by a highly distorted RhII complex with a new C3-symmetric tripodal tetraphosphine ligand      
            J. Wassenaar, B. de Bruin, M.A. Siegler, A.L. Spek, J.N.H. Reek,* J.I. van der Vlugt*
Chem. Commun. 2010, 46, 1232-1234.                                                               (14)

 

2009

29     Neutral tridentate PNP ligands and their hybrid analogues: Versatile (non-innocent) scaffolds for homogeneous catalysis
            J.I. van der Vlugt,* J.N.H. Reek
Angew. Chem. Int. Ed. 2009, 48, 8832-8846.                                                    (239)
invited minireview

28     Water splitting via cooperative catalysis
            D.G.H. Hetterscheid, J.I. van der Vlugt, B. de Bruin, J.N.H. Reek
Angew. Chem. Int. Ed. 2009, 48, 8178-8181.                                                     (54)

27     CuI complexes with a non-innocent CuI(PNP) complex: Selective dearomatization and electrophilic addition reactivity
            J.I. van der Vlugt,* E.A. Pidko, D. Vogt, M. Lutz, A.L. Spek
Inorg. Chem. 2009, 48, 7513-7515.                                                                    (43)
26     A cationic AgI(PNPtBu) species acting as PNP transfer agent: Facile synthesis of Pd(PNPtBu)(alkyl) complexes and their reactivity compared to PCPtBu analogues
            J.I. van der Vlugt,* M.A. Siegler, M. Janssen, D. Vogt, A.L. Spek
Organometallics 2009, 28, 7025-7032.                                                              (40)

25     Highly selective cobalt-catalyzed hydrovinylation of vinylarenes
            M.M.P. Grutters, J.I. van der Vlugt, Y. Pei, A.M. Mills, M. Lutz, A.L. Spek, C. Müller, C. Moberg, D. Vogt
Adv. Synth. Catal. 2009, 351, 2199-2208.                                                                     (36)

24     Dinuclear complexes with functionalized pyrazolate ligands
            A. Kumar Singh, J.I. van der Vlugt, S. Demeshko, S. Dechert, F. Meyer
Eur. J. Inorg. Chem. 2009, 3431-3439.                                                               (19)

23     Solid-solid phase transition in [Ni(OAc)(PNPtBu)]OTf leading to six independent molecules in the asymmetric unit
            M. Lutz, J.I. van der Vlugt, D. Vogt, A.L. Spek
Polyhedron 2009, 28, 2341-2346.                                                                                    (9)

22     Cationic and neutral NiII complexes derived from a non-innocent PNP ligand: Formation of alkyl and thiolate species and their reactivity
            J.I. van der Vlugt,* M. Lutz, E.A. Pidko, D. Vogt, A.L. Spek
Dalton Trans. 2009, 1016-1023.                                                                         (52)


2008

21     T-shaped cationic CuI complexes with hemilabile PNP-type ligands
            J.I. van der Vlugt,* E.A. Pidko, D. Vogt, M. Lutz, A.L. Spek, A. Meetsma        
Inorg. Chem. 2008, 47, 4442-4444.                                                                    (42)

20     Tetranuclear CoII, MnII and CuII complexes of a novel binucleating pyrazolate ligand preorganized for the self-assembly of compact [2´2] grid structures
            J.I. van der Vlugt, S. Demeshko, S. Dechert, F. Meyer
Inorg. Chem. 2008, 47, 1576-1585.                                                                    (57)

 

2007

19     Platinum-catalyzed hydroformylation of terminal and internal octenes
            R. van Duren, J.I. van der Vlugt, A.M. Mills, A.L. Spek, D. Vogt
Dalton Trans. 2007, 1053-1059.                                                                         (37)

18     Chelate control of diiron(I) dithiolates relevant to the Fe-only hydrogenase active site
            A.K. Justice, G. Zampella, L. de Goia, T.B. Rauchfuss, J.I. van der Vlugt, S.R. Wilson
Inorg. Chem. 2007, 46, 1655-1664.                                                                   (104)


2006

17     Chiral diphosphonite platinum complexes in asymmetric hydroformylation
            R. van Duren, L.J.J.M. Cornelissen, J.I. van der Vlugt, J.P.J. Huibers, A.M. Mills, A.L. Spek, C. Müller, D. Vogt
Helv. Chim. Acta 2006, 89, 1547-1558                                                               (19)

16     Electron-rich diferrous-phosphane-thiolates relevant to Fe-only hydrogenase: Is cyanide “nature's trimethylphosphane”?
            J.I. van der Vlugt, T.B. Rauchfuss, S.R. Wilson
Chem. Eur. J. 2006, 12, 90-98.                                                                           (46)

 

2005

15     Synthesis and applications of chiral phosphite ligands derived from incompletely condensed silsesquioxane backbones
            G. Ionescu, J.I. van der Vlugt, H.C.L. Abbenhuis, D. Vogt      
Tetrahedron: Asymmetry 2005, 16, 3970-3975.                                                   (27)

14     Characterization of a diferrous terminal hydride mechanistically relevant to the Fe-only hydrogenases
            J.I. van der Vlugt, T.B. Rauchfuss, C.M. Whaley, S.R. Wilson
J. Am. Chem. Soc. 2005, 127, 16012-16013.                                                         (112)

13     Platinum complexes of rigid bidentate phosphine ligands in the hydroformylation of 1-octene
            J.I. van der Vlugt, R. van Duren, G.D. Batema, R. den Heeten, A. Meetsma, J. Fraanje, K. Goubitz, P.C.J. Kamer, P.W.N.M. van Leeuwen, D. Vogt
Organometallics 2005, 24, 5377-5382.                                                   (32)

12     Diferrous cyanides as models for the Fe-only hydrogenases
            C.A. Boyke, J.I. van der Vlugt, T.B. Rauchfuss, S.R. Wilson, G. Zampella, L. de Gioia
J. Am. Chem. Soc. 2005, 127, 11010-11018.                                                       (55)

11     Disperse amphiphilic submicron particles as non-covalent supports for cationic homogeneous catalysts
            R. Sablong, J.I. van der Vlugt, R. Thomann, S. Mecking, D. Vogt
Adv. Synth. Catal. 2005, 347, 633-636                                                              (11)

10     Chiral bidentate aminophosphine ligands: Synthesis, coordination chemistry and asymmetric catalysis
            E.J. Zijp, J.I. van der Vlugt, D.M. Tooke, A.L. Spek, D. Vogt
Dalton Trans. 2005, 512-517.                                                                             (32)


2004

9       Coordination chemistry and asymmetric catalysis with a chiral diphosphonite
            J.I. van der Vlugt, J.M.J. Paulusse, E.J. Zijp, J.A. Tijmensen, A.M. Mills, A.L. Spek, C. Claver, D. Vogt
Eur. J. Inorg. Chem. 2004, 4193-4201.                                                               (20)

8       Sterically demanding diphosphonite ligands – synthesis and application in nickel catalyzed isomerization of 2-methyl-3-butenenitrile
            J.I. van der Vlugt, A.C. Hewat, S. Neto, R. Sablong, A.M. Mills, A.L. Spek, C. Müller, D. Vogt
Adv. Synth. Catal. 2004, 346, 993-1003.                                                                       (64)

7       Rhodium complexes of sterically constrained diphosphonites – coordination chemistry and catalysis
            J.I. van der Vlugt, R. Sablong, P.C.M.M. Magusin, A.M. Mills, A.L. Spek, D. Vogt
Organometallics 2004, 23, 3177-3183.                                                              (39)

6       Versatile phosphite ligands based on silsesquioxane backbones
            J.I. van der Vlugt, J. Ackerstaff, T.W. Dijkstra, A.M. Mills, H. Kooijman, A.L. Spek, A. Meetsma, H.C.L. Abbenhuis, D. Vogt
Adv. Synth. Catal. 2004, 346, 399-412.                                                             (24)

 

2003

5       Coordination chemistry and X-ray studies with novel sterically constrained diphosphonite ligands
            J.I. van der Vlugt, R. Sablong, A.M. Mills, H. Kooijman, A.L. Spek, A. Meetsma, D. Vogt
Dalton Trans. 2003, 4690-4699.                                                                         (30)

4       A silsesquioxane-based diphosphinite ligand – synthesis, DFT study and coordination chemistry
            J.I. van der Vlugt, M. Fioroni, J. Ackerstaff, R.W.J.M. Hanssen, A.M. Mills, A.L. Spek, A. Meetsma, H.C.L. Abbenhuis, D. Vogt
Organometallics 2003, 22, 5297-5306.                                                              (15)

3       New diphosphane ligands based on bisphenol A backbones - synthesis and coordination chemistry
            J.I. van der Vlugt, M.M.P. Grutters, A.M. Mills, H. Kooijman, A.L. Spek, D. Vogt
Eur. J. Inorg. Chem. 2003, 4361-4369.                                                               (22)

2       POSSphites – monophosphites derived from incompletely condensed silsesquioxanes
            J.I. van der Vlugt, M.M.P. Grutters, J. Ackerstaff, R.W.J.M. Hanssen, H.C.L. Abbenhuis, D. Vogt
Tetrahedron Lett. 2003, 44, 8301-8305.                                                             (11)

1       Modular diphosphine ligands based on bisphenol A backbones
            J.I. van der Vlugt, J.M. Bonet, A.M. Mills, A.L. Spek, D. Vogt
Tetrahedron Lett. 2003, 44, 4389-4392.                                                             (22)


Contributions to Books

4          Supramolecular bidentate phosphorus ligands
            J.I. van der Vlugt, J.N.H. Reek
Phosphorus(III) Ligands in Homogeneous Catalysis 2012, 427-462.                     (-)
(Eds. P.C.J. Kamer, P.W.N.M. van Leeuwen)
3          Chemistry in self-assembled reactors
J.I. van der Vlugt, T.S. Koblenz, J. Wassenaar, J.N.H. Reek                              
Molecular Encapsulation: Reactions in Constrained Systems 2010, 145-174.   (12)
(Eds. J.-L. Mieusset, U.H. Brinker)

2          Homogeneous copper-catalyzed oxidations
            J.I. van der Vlugt, F. Meyer
Top. Organomet. Chem. 2007, 22, 191-240.                                                       (27)
(Eds. F. Meyer, C. Limberg)

1          Synthetic models for the active sites of nickel-containing enzymes
            J.I. van der Vlugt, F. Meyer
Met. Ions Life Sci. 2007, 2, 181-240.                                                                  (12)
(Eds. A. Sigel, H. Sigel, R.K.O. Sigel)