Chemistry - A European Journal
[Co(TPP)]-Catalyzed Formation of Substituted Piperidines, Marianne Lankelma, Astrid M. Olivares, Bas de Bruin, Chem. Eur. J., 2019, accepted, DOI: 10.1002/chem.201900587

Chemistry - A European Journal
Uncatalysed Oxidative C-H Amination of 9,10-Dihydro-9-Heteroanthracenes: A Mechanistic Study, Nicolaas P. van Leest, Lars Grooten, Jarl Ivar van der Vlugt, Bas de Bruin, Chem. Eur. J., 2019, accepted, DOI: 10.1002/chem.201900377

Angewandte Chemie Int. Ed.
Interconversion of Phosphinyl Radical and Phosphinidene Complexes by Proton Coupled Electron Transfer, Josh Abbenseth, Daniel Delony, Marc C. Neben, Christian Würtele, Bas de Bruin, Sven Schneider, Angew. Chem. Int. Ed., 2019, accepted, DOI: 10.1002/anie.201901470

Inorganic Chemistry
Iron-Catalyzed/Mediated C-N Bond Formation: Competition between Substrate Amination and Ligand Amination, Suman Sinha, Rina Sikari, Vivek Sinha, Upasona Jash, Siuli Das, Paula Brandão, Serhiy Demeshko, Franc Meyer, Bas de Bruin, and Nanda D. Paul, Inorg. Chem., 2019, 58 (3), 1935-1948, DOI: 10.1021/acs.inorgchem.8b02877

Chemical Science
A low-valent dinuclear ruthenium diazadiene complex catalyzes the oxidation of dihydrogen and reversible hydrogenation of quinones, X. Yang, T. L. Gianetti, M. D. Wörle, N. P. van Leest, B. de Bruin, H. Grützmacher, Chem. Sci., 2019, 10, 1117-1125, DOI: 10.1039/C8SC02864H

Journal of the American Chemical Society
DFT Provides Insight into the Additive-Free Conversion of Aqueous Methanol to Dihydrogen Catalyzed by [Ru(trop2dad)]: Importance of the (Electronic) Flexibility of the Diazadiene Moiety, Vivek Sinha, Monica Trincado, Hansjörg Grützmacher, and Bas de Bruin, J. Am. Chem. Soc., 2018, 140(40), 13103-13114, DOI: 10.1021/jacs.8b09011

Macromolecules
Aqueous Phase Separation Behavior of Highly Syndiotactic, High Molecular Weight Polymers with Densely Packed Hydroxy-Containing Side Groups, Dorette S. Tromp, Marianne Lankelma, Hannah de Valk, Emile de Josselin de Jong, and Bas de Bruin, Macromolecules, 2018, 51(18), 7248-7256, DOI: 10.1021/acs.macromol.8b01150

Angewandte Chemie
Aryldiazonium Salts as Nitrogen-Based Lewis Acids: Facile Synthesis of Tuneable Azophosphonium Salts, Evi R. M. Habraken Nicolaas, P. van Leest, Pim Hooijschuur, Bas de Bruin, Andreas W. Ehlers, Martin Lutz, J. Chris Slootweg, Angewandte Chemie Int. Ed. 57(37), 2018, 11929-11933, DOI: 10.1002/anie.201806913

Synlett
Radical-type Reactions Controlled by Cobalt: From Carbene Radical Reactivity to the Catalytic Intermediacy of Reactive o-Quinodimethanes), Dirk Herrmann, Christian Rödl, Bas de Bruin, Frantisek Hartl, Robert Wolf, Synlett 2018; 29(17): 2238-2250, DOI: 10.1055/s-0037-1610204

Dalton Transactions
Synthesis, electronic structure and redox properties of the diruthenium sandwich complexes [Cp*Ru(µ-C10H8)RuCp*]x (x = 0, 1+; Cp* = C5Me5; C10H8 = naphthalene), Dirk Herrmann, Christian Rödl, Bas de Bruin, Frantisek Hartl, Robert Wolf, Dalton Trans., 2018, 47, 11058-11069, DOI: 10.1039/C8DT02003E

Inorganica Chimica Acta
Reactivity of Rhodium(II) amido/Rhodium(I) aminyl complexes, Nan Zhang, Di Zhu, David E. Herbert, Nicolaas P. van Leest, Bas de Bruin, Peter H.M. Budzelaar, Inorganica Chimica Acta, 2018, 482, 709-716, DOI: 10.1016/j.ica.2018.06.015

ACS Catalysis
How Solvent Affects C-H Activation and Hydrogen Production Pathways in Homogeneous Ru-Catalyzed Methanol Dehydrogenation Reactions, Vivek Sinha, Nitish Govindarajan, Bas de Bruin, and Evert Jan Meijer, ACS Catal., 2018, 8(8), 6908-6913, DOI: 10.1021/acscatal.8b01177

Photochemical & Photobiological Sciences (‘Hot Paper’)
Pump-probe XAS investigation of the triplet state of Ir photosensitizers with chromenopyridinone ligands, Grigory Smolentsev, Kaj M.van Vliet, Nicolo Azzaroli, Jeroen A. van Bokhoven, Albert M. Brouwer, Bas de Bruin, Maarten Nachtegaal and Moniek Tromp, Photochem. Photobiol. Sci., 2018,17, 896-902, DOI: 10.1039/C8PP00065D

Chemistry - A European Journal (‘Hot Paper’)
Mechanism of the Dehydrogenative Phenothiazination of Phenols, Monalisa Goswami, Alexander Konkel, Maryam Rahimi, Marie-Laure Louillat-Habermeyer, Harald Kelm, Rongwei Jin, Bas de Bruin, Frederic W. Patureau, Chem. Eur. J., 2018, 24(46), 11936-11943, DOI: 10.1002/chem.201800730 (10.1002/chem.201884669)

Chemistry - A European Journal (Frontispiece)
Mechanism of the Dehydrogenative Phenothiazination of Phenols, Monalisa Goswami, Alexander Konkel, Maryam Rahimi, Marie-Laure Louillat-Habermeyer, Harald Kelm, Rongwei Jin, Bas de Bruin, Frederic W. Patureau, Chem. Eur. J., 2018, 24(46), 11936, DOI: 10.1002/chem.201884669 (10.1002/chem.201800730)

Chemical Science
An iridium(III/IV/V) redox series featuring a terminal imido complex with triplet ground state, Markus Kinauer, Martin Diefenbach, Heiko Bamberger, Serhiy Demeshko, Edward J. Reijerse, Christian Volkmann, Christian Würtele, Joris van Slageren, Bas de Bruin, Max C. Holthausen, Sven Schneider, Chem. Sci., 2018, 9, 4325-4332, DOI: 10.1039/C8SC01113C

European Journal of Inorganic Chemistry ('Very Important Paper')
[Co(MeTAA)] Metalloradical Catalytic Route to Ketenes via Carbonylation of Carbene Radicals, Andrei Chirila, Kaj M. van Vliet, Nanda D. Paul, Bas de Bruin, European Journal of Inorganic Chemistry (2018), 2018(20-21), 2251-2258, DOI: 10.1002/ejic.201800101

European Journal of Inorganic Chemistry (Front Cover)
[Co(MeTAA)] Metalloradical Catalytic Route to Ketenes via Carbonylation of Carbene Radicals (Eur. J. Inorg. Chem. 20-21/2018), Andrei Chirila, Kaj M. van Vliet, Nanda D. Paul, Bas de Bruin, European Journal of Inorganic Chemistry (2018), 2018(20-21), 2060, DOI: 10.1002/ejic.201800608

European Journal of Inorganic Chemistry
Nickel-Alkyl Complexes with a Reactive PNC-Pincer Ligand, Linda S. Jongbloed, Nicolas Vogt, Aaron Sandleben, Bas de Bruin, Axel Klein, Jarl Ivar van der Vlugt, European Journal of Inorganic Chemistry (2018), 2018(20-21), 2408-2418, DOI: 10.1002/ejic.201800168

Molecules (Special issue 'Radical Chemistry’)
Porphyrin Co(III)-nitrene radical mediated pathway for synthesis of o-aminoazobenzenes, Monalisa Goswami and Bas de Bruin, Molecules 2018, 23(5), 1052, DOI: 10.3390/molecules23051052

Chemistry - A European Journal (‘Hot Paper’)
Ligand- and Metal-Based Reactivity of a Neutral Ruthenium Diolefin Diazadiene Complex: The Innocent, the Guilty and the Suspicious (Chem. Eur. J. 21/2018), Vivek Sinha, Bruno Pribanic, Bas de Bruin, Monica Trincado, Hansjörg Grützmacher, Chem. Eur. J., 2018, 24(21), 5513-5521, DOI: 10.1002/chem.201705957 (10.1002/chem.201800438)

Chemistry - A European Journal (Cover Profile)
Ligand- and Metal-Based Reactivity of a Neutral Ruthenium Diolefin Diazadiene Complex: The Innocent, the Guilty and the Suspicious (Chem. Eur. J. 21/2018), Vivek Sinha, Bruno Pribanic, Bas de Bruin, Monica Trincado, Hansjörg Grützmacher, Chem. Eur. J., 2018, 24(21), 5400, DOI: 10.1002/chem.201705957 (10.1002/chem.201800438)

Chemistry - A European Journal (Front Cover)
Ligand- and Metal-Based Reactivity of a Neutral Ruthenium Diolefin Diazadiene Complex: The Innocent, the Guilty and the Suspicious (Chem. Eur. J. 21/2018), Vivek Sinha, Bruno Pribanic, Bas de Bruin, Monica Trincado, Hansjörg Grützmacher, Chem. Eur. J., 2018, 24(21), 5396, DOI: 10.1002/chem.201800438 (10.1002/chem.201705957)

Chemistry - A European Journal (Special Issue: ECOSTBio - Spin States and Reactivity)
Catalytic Synthesis of Indolines via Hydrogen Atom Transfer to Cobalt(III)-Carbene Radicals, Alexander S. Karns, Monalisa Goswami, Bas de Bruin, Chem. Eur. J., 2018, 24(20), 5253-5258, DOI: 10.1002/chem.201704626

Journal of Catalysis
Mechanistic investigations into the cyclopropanation of electron deficient alkenes with ethyl diazoacetate using [Co(MeTAA)], Andrei Chirila, Maria B. Brands, Bas de Bruin, Journal of Catalysis, 2018, 361, 347-360, DOI: 10.1016/j.jcat.2018.02.013

Angewandte Chemie
Catalytic Dibenzocyclooctene Synthesis via Cobalt(III)-Carbene Radical and ortho-Quinodimethane Intermediates, Colet te Grotenhuis, Naudin van den Heuvel, Jarl Ivar van der Vlugt, Bas de Bruin, Angewandte Chemie Int. Ed. 57(1), 2018, 140-145, DOI: 10.1002/anie.201711028

Angewandte Chemie (Frontispiece)
Catalytic Dibenzocyclooctene Synthesis via Cobalt(III)-Carbene Radical and ortho-Quinodimethane Intermediates, Colet te Grotenhuis, Naudin van den Heuvel, Jarl Ivar van der Vlugt, Bas de Bruin, Angewandte Chemie Int. Ed. 57(1), 2018, 140-145, DOI: 10.1002/anie.201880161 (10.1002/anie.201711028)

European Journal of Inorganic Chemistry
Coordination of 3-Methylindole-Based Tripodal Tetraphosphine Ligands to Iron(+II), Cobalt(+II), and Nickel(+II) and Investigations of their Subsequent Two-Electron Reduction, Fenna F. van de Watering, Wowa Stroek, Jarl Ivar van der Vlugt, Bas de Bruin, Wojciech I. Dzik, Joost N. H. Reek, European Journal of Inorganic Chemistry (2018), 2018(11), 1254-1265, DOI: 10.1002/ejic.201701209

European Journal of Inorganic Chemistry
Application of [Co(Corrole)]- Complexes in Ring-Closing C-H Amination of Aliphatic Azides via Nitrene Radical Intermediates, Monalisa Goswami, Paul Geuijen, Joost N. H. Reek, Bas de Bruin, European Journal of Inorganic Chemistry (2018), 2018(5), 617-626, DOI: 10.1002/ejic.201701343

ChemCatChem
Importance of the Reducing Agent in Direct Reductive Heck Reactions, Saeed Raoufmoghaddam, Subramaniyan Mannathan, Adriaan J. Minnaard, Johannes G. de Vries, Bas de Bruin, Joost N. H. Reek, ChemCatChem (2018), 10(1), 266-272, DOI: 10.1002/cctc.201701206

Chemistry - A European Journal (‘Hot Paper’; Inside Front Cover)
Electrocatalytic Azide Oxidation Mediated by a Rh(PNP) Pincer Complex, Christophe Rebreyend, Yann Gloaguen, Martin Lutz, Jarl Ivar van der Vlugt, Inke Siewert, Sven Schneider and Bas de Bruin, Chem. Eur. J., 2017, 23(69), 17438-17443, DOI: 10.1002/chem.201704491 (10.1002/chem.201702938)

Chemistry - A European Journal (‘Hot Paper’)
Electrocatalytic Azide Oxidation Mediated by a Rh(PNP) Pincer Complex, Christophe Rebreyend, Yann Gloaguen, Martin Lutz, Jarl Ivar van der Vlugt, Inke Siewert, Sven Schneider and Bas de Bruin, Chem. Eur. J., 2017, 23(69), 17438-17443, DOI: 10.1002/chem.201702938

Chemistry - A European Journal (Concept paper. Frontispiece)
Nitrene Radical Intermediates in Catalytic Synthesis, Petrus F. Kuijpers, Jarl Ivar van der Vlugt, Sven Schneider and Bas de Bruin, Chemistry - A European Journal (2017), 23(56), 13819-13829, DOI: 10.1002/chem.201785661

Chemistry - A European Journal
Transition-Metal-Free Cleavage of CO, Marc Devillard, Bas de Bruin, Maxime A. Siegler, J. I. van der Vlugt, Chemistry - A European Journal 2017, 23(55), 13628-13632, DOI: 10.1002/chem.201703798

Chemistry - A European Journal (Concept paper)
Nitrene Radical Intermediates in Catalytic Synthesis, Petrus F. Kuijpers, Jarl Ivar van der Vlugt, Sven Schneider and Bas de Bruin, Chemistry - A European Journal (2017), 23(56), 13819-13829, DOI: 10.1002/chem.201702537

Organometallics (Front Cover)
Balance between Metal and Ligand Reduction in Diiminepyridine Complexes of Ti, Rahimi, N.; de Bruin, B.; Budzelaar, P.H.M., Organometallics, 2017, 36 (17), 3189-3198, DOI: 10.1021/acs.organomet.7b00239

Organometallics
Balance between Metal and Ligand Reduction in Diiminepyridine Complexes of Ti, Rahimi, N.; de Bruin, B.; Budzelaar, P.H.M., Organometallics, 2017, 36 (17), 3189-3198, DOI: 10.1021/acs.organomet.7b00239

Chemistry - A European Journal (‘Very Important Paper’; Inside Back Cover)
Cobalt-Porphyrin-Catalysed Intramolecular Ring-Closing C-H Amination of Aliphatic Azides: A Nitrene-Radical Approach to Saturated Heterocycles (Chem. Eur. J. 33/2017), Petrus F. Kuijpers, Martijn J. Tiekink, Willem B. Breukelaar, Daniël L. J. Broere, Nicolaas P. van Leest, Jarl Ivar van der Vlugt, Joost N. H. Reek and Bas de Bruin, Chemistry - A European Journal (2017), 23(33), 8099, DOI: 10.1002/chem.201701400

Chemistry - A European Journal (‘Very Important Paper’)
Cobalt-Porphyrin-Catalysed Intramolecular Ring-Closing C-H Amination of Aliphatic Azides: A Nitrene-Radical Approach to Saturated Heterocycles, Petrus F. Kuijpers, Martijn J. Tiekink, Willem B. Breukelaar, Daniël L. J. Broere, Nicolaas P. van Leest, Jarl Ivar van der Vlugt, Joost N. H. Reek and Bas de Bruin, Chemistry - A European Journal (2017), 23(33), 7945-7952, DOI: 10.1002/chem.201700358

Chemistry - A European Journal (‘Hot Paper’; Inside Back Cover)
A Stable Aminyl Radical Coordinated to Cobalt, Rafael E. Rodríguez-Lugo, Bas de Bruin, Monica Trincado and Hansjörg Grützmacher, Chem. Eur. J., 2017, 23(28), 6937, DOI: 10.1002/chem.201701240 (10.1002/chem.201605624)

Chemistry - A European Journal
A Stable Aminyl Radical Coordinated to Cobalt, Rafael E. Rodríguez-Lugo, Bas de Bruin, Monica Trincado and Hansjörg Grützmacher, Chem. Eur. J., 2017, 23(28), 6795-6802, DOI: 10.1002/chem.201605624

ChemCatChem
Diastereoselective Radical-Type Cyclopropanation of Electron Deficient Alkenes Mediated by the Highly Active [Co(MeTAA)] Catalyst, Andrei Chirila, Braja Gopal Das, Nanda D. Paul, Bas de Bruin, ChemCatChem, 2017, 9(8), 1358, DOI: 10.1002/cctc.201700556 (10.1002/cctc.201601568)

ChemCatChem (Front Cover)
Diastereoselective Radical-Type Cyclopropanation of Electron Deficient Alkenes Mediated by the Highly Active [Co(MeTAA)] Catalyst, Andrei Chirila, Braja Gopal Das, Nanda D. Paul, Bas de Bruin, ChemCatChem, 2017, 9(8), 1356, DOI: 10.1002/cctc.201700552 (10.1002/cctc.201601568)

ChemCatChem
Diastereoselective Radical-Type Cyclopropanation of Electron Deficient Alkenes Mediated by the Highly Active [Co(MeTAA)] Catalyst, Andrei Chirila, Braja Gopal Das, Nanda D. Paul, Bas de Bruin, ChemCatChem, 2017, 9(8), 1413-1421, DOI: 10.1002/cctc.201601568

EurJOC
Metal-Catalysed Azidation of Organic Molecules, Monalisa Goswami and Bas de Bruin, Eur. J. Org. Chem. 2017, 2017(8), 1152-1176, DOI: 10.1002/ejoc.201601390

Topics in Catalysis
Hydroformylation of 1-Octene Mediated by the Cobalt Complex [CoH(dchpf)(CO)2], Alexander M. Kluwer, Michael J. Krafft, Ingo Hartenbach, Bas de Bruin, Wolfgang Kaim, Topics in Catalysis, 2016, 59 (19-20), 1787-1792, DOI: 10.1007/s11244-016-0699-3

Organometallics
Accessing the CpArNi(I) Synthon: Reactions with N-heterocyclic Carbenes, TEMPO, Sulfur, and Selenium, Uttam Chakraborty, Franziska Urban, Bernd Mühldorf, Christophe Rebreyend, Bas de Bruin, Niels van Velzen, Sjoerd Harder, and Robert Wolf, Organometallics, 2016, 35 (11), 1624-1631, DOI: 10.1021/acs.organomet.6b00084

Chemistry - A European Journal
Selective Co-Encapsulation Inside an M₆L₄ Cage, Stefan H. A. M. Leenders, René Becker, Tatu Kumpulainen, Bas de Bruin, Tomohisa Sawada, Taito Kato, Makoto Fujita and Joost N. H. Reek, Chemistry - A European Journal (2016), 22(43), 15468-15474, DOI: 10.1002/chem.201603017

ChemCatChem
Reactivity of a Ruthenium–Carbonyl Complex in the Methanol Dehydrogenation Reaction, Fenna F. van de Watering, Dr. Martin Lutz, Dr. Wojciech I. Dzik, Prof. Dr. Bas de Bruin and Prof. Dr. Joost N. H. Reek, ChemCatChem, 2016, 8(17), 2752 -2756, DOI: 10.1002/cctc.201600709

Chemistry - A European Journal
Localized Mixed-Valence and Redox Activity within a Triazole-Bridged Dinucleating Ligand upon Coordination to Palladium, Daniël L. J. Broere, Raoul Plessius, Dr. Joanne Tory, Dr. Serhiy Demeshko, Prof. Dr. Bas de Bruin, Dr. Maxime A. Siegler, Prof. Dr. Frantisek Hartl and Dr. Jarl Ivar van der Vlugt, Chem. Eur. J. 2016, 22(39),13965 -13975, DOI: 10.1002/chem.201601900

Inorganic Chemistry
Reversible Redox Chemistry and Catalytic C(sp3)-H Amination Reactivity of a Paramagnetic Pd Complex Bearing a Redox-Active o-Aminophenol-Derived NNO Pincer Ligand, Daniël L. J. Broere, Nicolaas P. van Leest, Bas de Bruin, Maxime A. Siegler, and Jarl Ivar van der Vlugt, Inorg. Chem., 2016, 55(17), 8603-8611, DOI: 10.1021/acs.inorgchem.6b01192

Inorganic Chemistry
Deprotonation Induced Ligand Oxidation in a Ni^II Complex of a Redox Noninnocent N¹-(2-Aminophenyl)benzene-1,2-diamine and Its Use in Catalytic Alcohol Oxidation, Rina Sikari, Suman Sinha, Upasona Jash, Siuli Das, Paula Brandão, Bas de Bruin, and Nanda D. Paul, Inorg. Chem., 2016, 55 (12), pp 6114-6123, DOI: 10.1021/acs.inorgchem.6b00646

Journal of the American Chemical Society
Co(III)-Carbene Radical Approach to Substituted 1H-Indenes, Braja Gopal Das, Andrei Chirila, Moniek Tromp, Joost N. H. Reek, and Bas de Bruin, J. Am. Chem. Soc. (2016), 138(28), 8968-8975, DOI: 10.1021/jacs.6b05434

ACS Catalysis
A Self-Assembled Molecular Cage for Substrate-Selective Epoxidation Reactions in Aqueous Media, Petrus F. Kuijpers, Matthias Otte, Maximilian Dürr, Ivana Ivanovic-Burmazovic, Joost N. H. Reek, and Bas de Bruin, ACS Catalysis (2016), 6(5), 3106-3112, DOI: 10.1021/acscatal.6b00283

Inorganic Chemistry
[CpArNi{Ga(nacnac)}]:An Open-Shell Nickel(I) Complex Supported by a Gallium(I) Carbenoid (CpAr = C5(C6H4-4-Et)5, nacnac = HC[C(Me)N-(C6H3)-2,6-iPr2]2), Uttam Chakraborty, Bernd Mühldorf, Niels J. C. van Velzen, Bas de Bruin, Sjoerd Harder and Robert Wolf, Inorg. Chem., 2016, 55(6), 3075-3078, DOI: 10.1021/acs.inorgchem.5b02979

European Journal of Inorganic Chemistry
Reactivity of Me-pma Rh(I)- and Ir(I)-complexes upon deprotonation and their application in catalytic carbene carbonylation reactions, Zhou Tang, Cristina Tejel, Marc Martinez de Sarasa Buchaca, Martin Lutz, Jarl Ivar van der Vlugt and Bas de Bruin, Eur. J. Inorg. Chem. (2016), 2016(7), 963-974, DOI: 10.1002/ejic.201501302

Catalysis Science & Technology
Reversible cyclometalation at Rh-I as a motif for metal-ligand bifunctional bond activation and base-free formic acid dehydrogenation, L. S. Jongbloed, B. de Bruin, J. N. H. Reek, M. Lutz, J. I. van der Vlugt, Catal. Sci. Technol. (2016), 6(5), 1320-1327, DOI: 10.1039/C5CY01505G

Inorganic Chemistry
Nucleophilicity and P−C Bond Formation Reactions of a Terminal Phosphanido Iridium Complex, Ángel L. Serrano, Miguel A. Casado, Miguel A. Ciriano, Bas de Bruin, José A. López and Cristina Tejel, Inorg. Chem., 2016, 55 (2), 828-839, DOI: 10.1021/acs.inorgchem.5b02301

Molecules
Porphyrin Cobalt(III) “Nitrene Radical” Reactivity; Hydrogen Atom Transfer from Ortho-YH Substituents to the Nitrene Moiety of Cobalt-Bound Aryl Nitrene Intermediates (Y = O, NH), Monalisa Goswami, Christophe Rebreyend and Bas de Bruin, Molecules 2016, 21(2), 242-257, DOI: 10.3390/molecules21020242