Controlled
& Catalytic Radical-type Transformations
In the field of paramagnetic organometallic
chemistry the group is developing the emerging research field of metalloradical catalysis. Radical-type
reactivity of open-shell organometallic complexes is a largely uncharted
research area. Increasing reports on their involvement in catalysis stimulated
a world-wide interest in their properties. EPR spectroscopy, in combination
with DFT, is used as a powerful technique to obtain detailed information about
the electronic structure and reactivity of these species. Several chemo-,
regio-, and even enantioselective catalytic radical-type organometallic
reactions with CoII metalloradicals
were disclosed.
The group disclosed previously unprecedented
redox non-innocent behaviour of carbenes and nitrenes. Such donor-induced
spin-density shifts from the metal to a reactive ‘actor’ ligand during
catalysis constitutes a fundamentally new approach to tune the catalytic
reactivity of open-shell transition metal-substrate complexes.
The group further contributed substantially to
charting the unusual metal and ligand centred radical-type reactivity of
open-shell organometallic compounds, which includes C-H, C-C, C-O and C-N bond making and breaking,
hydrogen-atom transfer reactions, unusual electro-isomerism (electromerism), water oxidation, controlled radical
polymerisation of acrylates, and a variety of related ligand-centred
transformations. Besides the metalloradical
reactivity of CoII, the group has ample
experience with IrII, RhII,
and Rh0 metallo-radicals and
ultra-reactive intermediates derived from these interesting compounds in the
presence of reactive substrates under catalytic conditions.
Cobalt-Catalysed
Hydrogenation Reactions
As part
of our efforts to replace expensive noble metals by cheaper, earth-abundant
ones, we recently started a project to replace rhodium- by cobalt-catalysts for
applications in hydrogenation reactions. These catalyst were recently shown to
be effective in catalytic hydrogenation of esters and carboxylic acids (Science
2015), thus circumventing stoichiometric reduction with aluminiumhydrides. We
are currently studying their activity in several other (de)hydrogenation
processes of interest to chemical industries and for energy-conversion
applications.
Carbene Polymerisation
Metallo-carbenes are well-known as important
intermediates in olefin cyclopropanation and olefin
metathesis reactions, but more recently it has become clear that their
chemistry is far richer. We demonstrated that metallo-carbenes
can be used in transition metal insertion polymerization to arrive at
completely new types of stereoregular carbon-chain
polymers Notably these new polymers
contain a polar functional side group at each
carbon of the polymer backbone. This new family of poly(substituted methylene)
polymers has a potential for the development of new materials, which are easily
modified to tune the material properties, for various possible applications.
We are now further investigating the mechanism
and scope of this remarkable new polymerisation reaction. We will use this new
concept to prepare new polymeric materials based on homo- and co-polymerisation
of (functionalized) carbenes, and we are investigating co-polymerisation of
carbenes with other reactive monomers. The obtained syndiotactic (co)polymers are
crystalline, and reveal interesting thermotropic and lyotropic liquid
crystalline properties.
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We are also trying to uncover new reactions in which carbene
(migratory) insertion reactions play a central role. DFT calculations suggest
that the transition state (TS) of the new carbene polymerisation reaction is
very similar to the TS’s of a variety of carbonyl insertion reactions. Based on
this analogy, we will investigate several new carbene insertion reactions,
potentially leading to new and useful polymeric materials and new synthetic
routes to prepare small functional organic molecules. Traditional ligand
screening & modification methods and new combinatorial and supramolecular
approaches (encapsulation) will be explored to arrive at new and improved
catalyst. DFT calculations will assist in gaining deeper mechanistic insights
required for the optimization of such new catalytic reactions.
Paint curing
In
collaboration with industry (AkzoNobel) within the ARC CBBC consortium the
group developed new Fe-based curing catalysts for alkyd paid drying (JACS Au
2022). These are latents catalyst that are activated by light. These systes
replace both Co and MEKO, which can cause health issues and hence are under
presure to be phased-out according to REACH regulations. This work has also led
to two patents thus far.
Short
CV
Bas de Bruin studied chemistry at the University of Nijmegen from
1989-1994. He obtained his Ph. D. (April 20, 1999) from the same university
(Rh Mediated Olefin Oxygenation). He did his postdoc in the group of Wieghardt at the Max-Planck Institut
für Bioanorganische Chemie
(Mülheim a/d Ruhr, Germany,
April 1999-April 2000) for which he obtained an Alexander-von-Humboldt fellowship
in 1999. After his postdoc he returned to the University of Nijmegen as an assistant professor in Inorganic Chemistry
(Metal-Organic Chemistry), where he was involved in several research activities
ranging from olefin oxygenation, radical organometallic chemistry, EPR
spectroscopy, catalysis, light-switchable redox bistable molecules, DFT
calculations, and (catalytic) synthesis of new materials. September 2005, Bas de Bruin obtained an NWO-VIDI
grant to uncover new catalytic reactions. November 2005 he moved to the
University of Amsterdam (UvA, group Reek, Homogeneous
and Supramolecular Catalysis), where he was promoted to Associate Professor
(UHD, October 2008). January 2013 he was promoted
to Full Professor (chair) at the same university. January 2016 he was
elected as ‘UvA teacher of the year 2015’, in a
university-broad competition organized by the students of the University of
Amsterdam. In 2020 he was elected as a Chemistry Europe Fellow.
Bas de Bruin presently focuses at the
development of new tools in homogeneous catalysis, using metals in
unconventional oxidation states and unconventional ligands, specifically aiming
at the development of new catalytic reactions. In 2008 he obtained a prestigious ERC Starting Grant (first
round of the EU 7th framework Ideas Program; ERC = European Research
Council). In 2012 he obtained a prestigious NWO-VICI grant to
investigate new controlled (catalytic) radical-type transformations. Bas de
Bruin is involved in teaching Inorganic Chemistry, Thermodynamics,
Organometallic Chemistry, Bioinorganic Chemistry, Homogeneous Catalysis and
(Catalytic) Reaction Mechanisms.
Non-Refereed
Publications, Editorials & Interviews
12. Non-innocent ligands
Berben,
L.A.; de Bruin, B.; Heyduk, A.F., Chem.
Commun., 2015, 51, 1553-1554.
Web Themed
Special Issue, Editorial.
[link]
11. Kennislink:
[link]
10. Oratie UvA:
[link]
9. Chemisch2weekblad (C2W) profiel Bas de Bruin (VICI
highlight)
Kosterman,
K.; de Bruin, B.; C2W. jrg 108, #3,
Febr. 2012, p38.
8. Angewandte Chemie Author
Profile Bas de Bruin
de Bruin, B.,
Angew. Chem. Int. Ed. 2012, 51,
1102.
[link]
7. Cooperative & Redox Non-Innocent Ligands in
Directing Organometallic Reactivity
Hindson, K..& de
Bruin, B., Eur. J. Inorg. Chem., 2012, 3, 340 – 342.
Editorial.
[link]
6. Electromeric Rhodium Radical Complexes
(highlight of paper)
CHIMIA 2010, 64, No. 4, 266.
5. Chemisch2weekblad (C2W): Elektromeren in Evenwicht
(highlight of 2 papers)
Dijkgraaf,
A.; de Bruin, B.; C2W. jrg 106, #1,
Jan. 2010, p9.
4. Highly functionalized polymers from carbenes by
Rh-mediated polymerization of diazoesters.
Jellema, E.; Reek, J. N. H.;
de Bruin, B.*; PMSE Preprints, 2009, 101, 1762 - 1763.
3. ERC subsidie Bas de Bruin en Sander Woutersen
Folia (weekblad
voor de Universiteit van Amsterdam), jaargang 61, 14-03-2008, Nr 24, P. 24-25.
[link]
2. Projects Magazine (British Publishers) online
profile (ERC Highlight)
[link]
1. Chemisch2weekblad (C2W) profiel Bas de Bruin
(Jonge Chemici Highlight)
Van der Wilt,
P.; de Bruin, B.; C2W. jrg 97, #23,
Dec. 2001, p37.
Books & Book Chapters
9. Mechanistic Studies of Catalytic Nitrene-Transfer Reactions
Involving Redox-Active Ligands and Substrates (Chapter 2, Pages 21-52). van Leest, N.P.; van der Vlugt, J.I.; de Bruin, B. in Redox-Active Ligands: Concepts
and Catalysis, Wiley Press, 2024 (edited by Marine Desage-El
Murr), ISBN: 978-3-527-83088-6.
Invited book Chapter.
[link]
8. Supramolecular Substrate Orientation as Strategy to Control Selectivity
in Transition Metal Catalysis (Chapter 12, Pages 161-177). Reek, J.N.H.; de Bruin,
B. in Supramolecular Catalysis: New
Directions and Developments, Wiley-VCH,
2022 (edited by: Piet W.N.M. van
Leeuwen & Matthieu Raynal), ISBN: 9783527349029.
Invited book Chapter.
[link]
7. Application of Stimuli Responsive and ‘Non-innocent’ Ligands in Base
Metal Catalysis (Chapter 1)
Chirila,
A.; Gopal Das, B.; Kuijpers, P.F.; Sinha, V.; de Bruin, B. in Non-Noble Metal Catalysis: Molecular
Approaches and Reactions, Wiley
Press, 2019 (edited by Klein Gebbink, R.J. & Moret, M.-E.), ISBN:
978-3-527-69908-7.
Invited book Chapter.
[link]
6. Single-Electron
Elementary Steps in Homogeneous Organometallic Catalysis (Chapter 2)
van Leest,
N.P.; Epping, R.F.J.; van Vliet, K.M.; Lankelma, M.;
van den Heuvel, E.J.; Heijtbrink, N.; Broersen, R.; de Bruin, B. in Advances in Organometallic Chemistry, 2018 vol 70. (edited by Pedro Pérez, P.).
Invited book Chapter.
[link]
5. Carbene or C1 Polymerization (Chapter 3)
de
Bruin, B. and Chikkali, S. H. in Metal-Catalyzed Polymerization: Fundamentals to Applications, CRC Press, 2018 (edited by Chikkali, S.H.), ISBN:
9781498767576.
Book Chapter.
[link]
4. Redox Non-innocent Ligands: Reactivity and Catalysis (Chapter 7)
de
Bruin, B.*; Gualco, P.; Paul, N.D., in Ligand
Design In Metal Chemistry: Reactivity and Catalysis, Wiley, (edited by Stradiotto, M. & Lundgren, R.),
2016, ISBN: 978-1-118-83983-6, p.46‑65.
Invited Book Chapter.
[link]
3. Multiple Spin State Scenarios in Organometallic Reactivity (Chapter
6)
Dzik, W.I.; Böhmer, W.;
de Bruin, B.* in
Spin States in Biochemistry and Inorganic
Chemistry: Influence on Structure and Reactivity, Wiley, (edited by Swart, M. & Costas, M.), 2015, ISBN:
978-1-118-89831-4, p.103 - 130.
Invited Book Chapter.
[link]
2. Open-Shell Organometallics: Reactivity at the Ligand
Dzik, W.I.; de Bruin,
B.* Specialist Periodical Report
Organometallic Chemistry, 2011, volume 37, p.46 - 78.
Invited Book Chapter.
[link]
1. The
Organometallic Chemistry of Rh, Ir, Pd and Pt based
Radicals; Higher Valent Species.
Hetterscheid, D.G.H.; Grützmacher,
H; Koekoek, A.J.J.; de Bruin, B.*; Progress in Inorganic Chemistry, 2007,
55, 247 - 253.
Invited Review/Book Chapter (included in Reuters WoS
citation lists).
[link]
Patents
3. COATING COMPOSITION COMPRISING AN AUTOXIDIZABLE RESIN AND
DRIER COMPRISING A TRANSITION METAL AND LIGAND
Bootsma, J.; de Bruin, B.; Flapper, J. EP24187022.9. Date: 8 July 2024.
2. COATING COMPOSITION COMPRISING AN AUTOOXIDIZABLE RESIN AND
AN IRON-LIGAND COMPLEX, SUBSTRATE COATED WITH SUCH COATING COMPOSITION, AND USE
OF SUCH IRON_LIGAND COMPLEX
Bootsma, J.; de Bruin, B.; Flapper, J. EPC 19184519.7 –
1107. Date: 27 August 2019.
1. FUNCTIONALIZED MATERIALS BY CATALYZED CARBENE COPOLYMERIZATION
Jellema, E.; Jongerius, A.L.; Fransen, N.G.M.; de Bruin, B.;
WO 2011/157444 A1; PCT/EP2011/003016. International
publication date: 22 December 2011.
Refereed Scientific
Publications
[Google Scholar]
[Scopus]
[ResearcherID]
[ORCID]
2024
316. Direct photopatterning of colloidal quantum
dots with electronically optimized diazirine crosslinkers
Fu,
Z; Musolino, S.; Qing, W.; Li, H.; de Zwart, F.; Zheng, Z.; Cai, M.; Gao, Y.;
de Bruin, B.; Dai, X.; Wulff, J.; Zhang, H. J. Am. Chem. Soc. 2024, 146, 42, 28895–28905.
[link]
315. Non-Kekulé meta-Quinodimethane Singlet Diradicals Based on Classical
N-Heterocyclic Carbenes
Steffenfauseweh, H.; Rottschäfer,
D.; Vishnevskiy, Y.V.; Neumann, B.; Stammler, H.G.; de Bruin, B.*, Ghadwal, R.S.* Chem. Eur. J. 2024, 30, e202403029 (7 pages).
[link]
314. Tuning Catalytic Performance of Platinum
Single Atoms by Choosing the Shape of Cerium Dioxide Supports
Laan,
P.C.M.; Mekkering, M.J.; de Zwart, F.J.; Troglia, A.;
Bliem, R.; Zhaoc, K.;
Geels, N.J.; de Bruin, B.; Rothenberg, G.; Reek, J.N.H.; Yan, N. Catalysis,
Science & technology, 2024, 14,
5662-5670.
[link]
313. Rapid and Scalable Photocatalytic
C(sp2)-C(sp3) Suzuki-Miyaura Cross-Coupling of Aryl
Bromides with Alkyl Boranes
Wang, T.; Capaldo, L.; Djossou, J.; Staffa,
A.; de Zwart, F.J.; de Bruin, B.; Noël, T. Nature
Communications, 2024, 15, 4028
[ChemRxiv]
[link]
312. Bright Future for New Iron-Based Alkyd Drier
Flapper,
J.. Bootsma, J.; de Bruin, B.; European Coatings Journal, 2024, 04, 32-35.
[link]
311. N-Heterocyclic Carbene Analogues of Wittig
Hydrocarbon
Steffenfauseweh, H.; Vishnevskiy, Y.;
Neumann, B.; Stammler, H.-G.; de Bruin, B.; Ghadwal,
R. Chem. Eur. J. 2024, e202400879
[link]
310. C–H Bond Activation by Iridium(III) and
Iridium(IV) Oxo Complexes
Tepaske, M.A.; Fitterer, A.; Verplancke, H.; Delony, D.; Neben, M.C.; de Bruin, B.;
Holthausen, M.C.; Schneider, S. Angew. Chem. Int.
Ed., 2024, 63,
e202316729
[link]
309. Meta-C−H Arylation of Aniline
Derivatives via Palladium/ S,O-Ligand/Norbornene Cooperative Catalysis
Sukowski, V.; van Borselen, M.; Mathew, S.; de Bruin, B.; Fernández-Ibáńez,
A. Angew. Chem. Int. Ed., 2024, 63, 5, e202317741
[link]
308. Copper-Catalyzed Sulfimidation
in Aqueous Media: a Fast, Chemoselective and
Biomolecule-Compatible Reaction
Meeus, E.J. Álvarez, M.; Koelman, E.; Pérez, P.J.; Reek, J.N.H.; de Bruin, B.* Chem.
Eur. J., 2024,
30, 14, e202303939
[link]
[ChemRxiv]
307. Isocyanate-Free
Polyurethane Coatings through Thermal Diazirine Curing
de Zwart, F.J.; Wolzak, L.A.; van den Berg, K.J.; Baran, M.J.;
Wulff, J.E.; Flapper, J.; de Bruin, B.* ACS Appl. Polym.
Mater. 2024,
6, 6, 3517–3522
[link]
306. Gas Evolution as a Tool to study Reaction
Kinetics under Biomimetic Conditions
Meeus, E.J.;
Laan, P.C.M. Ham, R. de Bruin, B.; Reek, J.N.H. XXXXX. 2023,
[ChemRxiv]
305. PhenTAA: A Redox-Active N4-Macrocyclic
Ligand Featuring Donor and Acceptor Moieties
Epping,
R.F.J.; de Zwart, F.J.; van Leest, N.P.; van der Vlugt,
J.I.; Siegler, M.A.; Mathew, S.; Reek, J.N.H.; de Bruin, B.* Inorg. Chem. 2024, 63, 4, 1974–1987.
[link]
304. Atom transfer radical addition of activated
primary alkyl chlorides using in situ generated [Cp*RuII(Cl)(PR3)] catalysts
van Leeuwen,
N.S.; Mathew, S.; van Lare, C.E.J.; Ahr, M.P.;
Zwijnenburg, A.; Pullen, S.; de Bruin, B.* ChemCatChem,
2024, e202301407
[link]
303. Cobalt Catalyzed Asymmetric Hydrogenation:
Substrate Specificity and Mechanistic Variability
Chakrabortty, S.; de Bruin, B.; de Vries, J.G. Angew. Chem. Int. Ed. 2024, 63, e20231577
[link]
2023
302. Concise
Synthesis of Azilect via Cobalt-Catalyzed
Enantioselective Hydrogenation in a Bio-Based Solvent
Chakrabortty,
S.; de Zwart, F.J.; Snabilié, D.; Balaraman, E.;
Reek, J.N.H.; de Bruin, B.; de Vries, J.G. Cat. Sci. & Techn. 2023, 13, 6668-6674
[link]
301. A
Co(TAML)-Based Artificial Metalloenzyme for Asymmetric Radical-Type Oxygen Atom
Transfer Catalysis
Meeus, E.J.; Igareta,
N.; Morita, I.; Ward, T.; de Bruin, B.; Reek, J.N.H. Chem. Commun. 2023,
[link]
[ChemRxiv]
300. Thermal/Blue light Induced Crosslinking of
Acrylic Coatings with Diazo Compounds
de
Zwart, F.J. Wolzak, L.A.; Laan, P.C.M.; Mathew, S.;
Flapper, J.; van den Berg, K.J.; Reek, J.N.H.; de Bruin, B.* Macromolecular Rapid Communications, 2023, 2300380
[link]
299. Understanding
the oxidative properties of nickel oxyhydroxide in alcohol oxidation reactions
Laan, P.; de Zwart, F.; Wilson, E.; Troglia, A.; Lugier, O.; Geels,
N. ; Bliem, R.; Reek, J.N.H.; de Bruin, B.; Rothenberg, G.; Yan, N. ACS Catalysis
2023, 13, 8467-8476.
[link]
298. In vivo
biodistribution of kinetically stable Pt2L4 nanospheres
that show anti-cancer activity
Bobylev, E.O.; Knol, R.A.; Mathew,
S.; Poole III, D.A.; Kotsogianni, I.; Martin, N.I.;
de Bruin, B.; Kros, A,; Reek, J.N.H. Chemical Science 2023, 14, 6943-6952.
DOI: 10.1039/d3sc01086d
[link]
297. Carbene Radicals in Transition-Metal-Catalyzed
Reactions.
Epping,
R.F.J.; Vesseur, D.; Zhou, M.; de Bruin, B.* ACS Catalysis 2023, 13, 5428−5448.
[link]
296. Understanding
Off-Cycle and Deactivation Pathways in Radical-Type Carbene Transfer Catalysis.
Snabilié,
D.D.; Meeus, E.J.; Epping, R.F.J.; He, Z.; Zhou, M.;
de Bruin, B.* Chem. Eur. J. 2023, 29, 30,
e202300336
[link]
295. The
application of M12L24 nanocages as cell-specific siRNA
delivery agents in vitro.
Bobylev, O.; Zheng, E.; Weijgertse, K.; Koelman, E.; Meijer, E.M.; de
Bruin, B., Kros, A.; Reek, J.N.H. Chem 2023, 9, 6, 1578-1593
[link]
294. Effector regulatated cyclization of alkynoic
acids using Pt2L4 cages.
Bobylev, O.; Ruiter,
J.; Poole, D.; Mathew, S.; de Bruin, B., Reek, J.N.H. Angew. Chem. Int. Ed. 2023, 62, e202218162.
[link]
293. Kinetic
protection of a water-soluble olefin metathesis
catalyst for potential use under biological conditions.
James, C.C.; Laan, P.C.M.;
de Bruin, B., Reek, J.N.H. ChemCatChem 2023, 15, e202201272. [link]
292. Thermal
and (thermo-reversible) photochemical cycloisomerization
of 1H-2-benzo[c]oxocins; From synthetic applications
to the development of a new T-type molecular photoswitch
Zhou, M. ; Mathew, S.;
de Bruin, B.* J. Am. Chem. Soc. 2023, 145, 1,
645–657.
[link] [ChemRxiv]
291. Photoinduced
Halogen-Atom Transfer by N-heterocyclic carbene-ligated boryl
radicals for C(sp3)−C(sp3) bond formation
Wan, T.; Capaldo, L.; Ravelli,
D.; Vitullo, W.; de Zwart, F.; de Bruin, B.; Noël, T.
J. Am. Chem. Soc. 2023, 145,
991–999
[link] [ChemRxiv]
290. Iron-Catalyzed
Intermolecular C–N Cross-Coupling Reactions via Radical Activation Mechanism
Das, S.; Ehlers, A.W.; Patra, S.; de Bruin, B.; Chattopadhyay,
B. J. Am. Chem. Soc. 2023, 145, 27,
14599–14607
[link]
289. Styrene
aziridination with [CoIII(TAMLred)]– in water: Understanding
and preventing epoxidation via nitrene hydrolysis
Meeus,
E.J.; Derks, M.T.G.M; van Leest, N.P.; Verhoef, C.J.; Roithova,
J.; Reek, J.N.H.; de Bruin, B.* Chem Catalysis, 2023, 3, 100700.
[link] [ChemRxiv]
288. Exposing
Mechanisms for Defect Clearance in Supramolecular Self-Assembly:
Palladium–Pyridine Coordination Revisited
Poole III, D.A.; Bobylev,
E.O.; de Bruin, B.; Mathew, S.; Reek, J.N.H. Inorg. Chem. 2023, 62, 14, 5458-5467.
[link]
287. Cobalt-Catalyzed
Enantioselective Hydrogenation of Trisubstituted Carbocyclic Olefins: An Access
to Chiral Cyclic Amides
Chakrabortty,
S.; Konieczny, K.; de Zwart, F.J.; Bobylev, E.O.; Baráth, E.; Tin, S.; Müller,
B.H.; Reek, J.N.H.; de Bruin, B.; de Vries, J.G. Angew.
Chem. Int. Ed. 2023, 62, 26, e202301329.
[link]
286. Creating
Conjugated C−C Bonds between Commercial Carbon Electrode and Molecular
Catalyst for Oxygen Reduction to Hydrogen Peroxide
Biemolt, J.; Meeus,
E.J.; de Zwart, F.J.; de Graaf, J.; Laan, P.C.M.; de Bruin, B.; Burdyny, T.; Rothenberg, G.; Yan, N. ChemSusChem 2023, 16 (18) , e202300841.
https://doi.org/10.1002/cssc.202300841
[link]
285. Transition
Metal Catalysis in Living Cells: Progress, Challenges, and Novel Supramolecular
Solutions
James, C.C. ; de Bruin, B. ; Reek,
J.N.H. Angew. Chem.
Int Ed. 2023, e202306645
[link]
284. A photoresponsive gold catalyst based on
azobenzene-functionalized NHC ligands
Liu, J,; Bobylev, E.O. de Bruin, B.; Reek, J.N.J. Chem. Commun. 2023, 59, 8830-8833. DOI: 10.1039/D3CC01726E
[link]
283. Dry
reforming of methane over single-atom Rh/Al2O3 catalysts prepared by exsolution
Mekkering, M.J.; Biemolt,
J.; de Graaf, J.; Lin, Y.-A. van Leest, N.P.; Troglia,
A.; Bliem, R.; de Bruin, B.; Rothenberg,
G.; Yan, N. Catal. Sci.
Technol. 2023, 13, 2255-2260. DOI: 10.1039/D2CY02126A
[link]
282. Enhancement
of London Dispersion in Frustrated Lewis Pairs: Towards a Crystalline Encounter
Complex
Holtrop, F.;
Helling, C.; Lutz, M.; van Leest, N.P.; de Bruin, B.;
Slootweg, J.C. Synlett 2023, 34 (10), 1122-1128.
[link]
2022
281. Isocyanate-Free Polyurea Synthesis via Ru-Catalyzed Carbene Insertion
into the N–H Bonds of Urea
de
Zwart, F.J.; Laan, P.C.M.; van Leeuwen, N.S.; Bobylev, E.O.; Amstalden van
Hove, E.R.; Mathew, S.; Yan, N.;
Flapper, J.; van den Berg, K.J.; Reek, J.N.H.; de Bruin, B.*
Macromolecules 2022, 55, 21, 9690–9696.
[link]
[ChemRxiv]
280. A Singlet-Diradical Co(III)-Dimer as a Nonvolatile Resistive Switching
Device: Synthesis, Redox-Induced Interconversion, and
Current–Voltage Characteristics
Sinha, S.;
Sahad E, M.; Mondal, R.; Das, S.; Manamel,
L.T.; Brandăo, P.; de Bruin, B.; Das, B.C.; Paul, N.D.
J. Am. Chem. Soc. 2022, 144, 44, 20442-20451.
[link]
279. Protection of a Gold Catalyst by a Supramolecular Cage Improves Bioorthogonality
James, C.C.;
Wu, D.; Bobylev, E.O.; Kros, A.; de Bruin, B.; Reek, J.N.H.
ChemCatChem 2022, 14,
e20220094.
[link]
278. M6L12 nanospheres with multiple C70
binding sites for 1O2 formation in organic and aqueous
media
Bobylev, E.O.; Poole III, D.A.; de Bruin, B.; Reek,
J.N.H.
J. Am. Chem. Soc. 2022, 144, 34, 15633–15642
[link]
277. The role of
structural vacancies in a Ti2CTx MXene-derived
catalyst for n-Butane Oxidative Dehydrogenation
Ronda-Lloret, M.; Slot, T. K.; van Leest, N. P.; de Bruin,
B.; Sloof, W.G.; Batyrev,
E.; Sepúlveda-Escribano, A.; Ramos-Fernandez, E.V.;
Rothenberg, G.; Shiju, N.R. ChemCatChem 2022, accepted.
[link]
276. Reactivity of a
Unique Si(I)-Si(I)-based η2-bis(silylene)
Iron Complex
He, Z.; de Zwart, F.J.; Xue, X.; Ehlers, A.W.; Yan, K.; Demeshko, S.; van der Vlugt,
J.I.*; de Bruin, B.*; Krogman, J.P.* Inorg. Chem. 2022,
61, 30, 11725–11733.
[link]
275. Transition Metal
Catalysis Controlled by Hydrogen Bonding in the Second Coordination Sphere
Reek, J.N.H.; de Bruin, B.; Pullen,
S.; Mooibroek, T.J.; Kluwer, A.M.; Caumes, X. Chemical Reviews 2022, 122,
14, 12308–12369
[link]
274. Cobalt(II)–tetraphenylporphyrin-catalyzed carbene transfer from
acceptor-acceptor iodonium ylides via N-enolate carbene radicals
Epping, R.F.J; Hoeksma, M.M.;
Bobylev, E.O.; Mathew, S.; de Bruin, B.* Nature Chemistry 2022,
14, 550–557. DOI:
10.1038/s41557-022-00905-4.
[link]
[Free-to-Read
Full-Text Link] [ChemRxiv] [FigShare]
273. Computational Mechanistic Studies of Ruthenium
Catalysed Methanol Dehydrogenation
de Zwart,
F.J.; Sinha, V.*; Trincado, M.; Grützmacher,
H.; de Bruin, B.* Dalton Trans. 2022, 51, 3019-3026.
Hot Article (quarterly
HOT article collection)
[link]
272. Combining metal–metal cooperativity,
metal–ligand cooperativity and chemical non-innocence in diiron carbonyl
complexes
van Beek, C.B.; van Leest, N.P.; Lutz, M.; de Vos, S.D.; Klein Gebbink,
R.J.M.; de Bruin, B.; Broere, D.L.J. Chem. Sci. 2022, 13, 2094-2104.
[link]
271. Exogenous Ligand-Free Nickel-Catalyzed
Carboxylate O-Arylation: Insight into NiI/NiIII Cycles
Wolzak, L.A.; de Zwart, F.J. Oudsen, J.-P.H.
Bartlett, S.A. de Bruin, B.; Reek, J.N.H. Tromp, M. Korstanje, T.J. ChemCatChem
2022, 14, e2022005.
[link] [ChemRxiv]
270. A Photo-Active Fe Catalyst for Light-triggered Alkyd Paint Curing
Bootsma, J.; Browne, W.R.; Flapper, J.; de Bruin, B.* JACS
Au 2022, 2, 2, 531–540.
[link]
269. Peptide cyclisation promoted by supramolecular complex formation
Hartendorp, A.P.T.; de Zwart, F.J.; Bieräugel,
H.; de Bruin, B.; Reek, J.N.H., van Maarseveen, J.H. Org.
Biom. Chem. 2022, 20, 575-578.
[link]
268. Boosting Electrochemical Oxygen Reduction Performance of Iron
Phthalocyanine through Axial Coordination Sphere Interaction
Zhang, W.; Meeus, E.J.; Wang, L.;
Zhang, L.-H. Yang, S.; de Bruin, B.*; Reek, J.N.H.; Yu,
F.*
ChemSusChem. 2022, e202102379.
[link]
2021
267. Three-State Switching of an Anthracene Extended Bis-thiaxanthylidene with a Highly Stable Diradical State
Wonink, M.; Corbet, B.P.; Kulago, A.A.; Boursalian, G.B.; de Bruin, B.; Otten, E.; Browne, W.R.;
Feringa, B.L. J. Am. Chem. Soc. 2021, 143, 18020−18028.
[link]
266. Catalytic Formation of Coordination-Based Self-Assemblies by Halide
Impurities
Bobylev, E.O.; de Bruin, B.; Reek, J.N.H. Inorg.
Chem. 2021, 60 (16), 12498–12505.
[link]
265. Catalytic synthesis of 1H-2-benzoxocins;
Cobalt(III)-carbene radical approach to 8-membered heterocyclic enol ethers
Zhou, M.; Wolzak, L.A. Li, Z.; de
Zwart, F.J. Mathew, S.; de Bruin, B.* J.
Am. Chem. Soc. 2021, 143, 48, 20501–20512. DOI:
https://doi.org/10.1021/jacs.1c10927
[link] [ChemRxiv]
264. Di-tert-butyldiphosphatetrahedrane as a Source
of 1,2 Diphosphacyclobutadiene Ligands
Hierlmeier, G.; Coburger, P.; Scott,
D.J.; Maier, T.M.; Pelties, S.; Wolf, R.; Pividori, D.; Meyer, K.; van Leest, N.P.; de Bruin, B. Chem. Eur. J. 2021, 27 (60), 14936-14946.
[link]
263. Controlling Radical-Type Single-Electron Elementary Steps in Catalysis
with Redox-Active Ligands and Substrates
van Leest, N.P. de Zwart, F.J.; Zhou,
M.; de Bruin, B.* JACS Au, 2021,
1, 8, 1101–1115.
[link]
262. Photo-Initiated Cobalt Catalyzed Radical Olefin Hydrogenation
Sang, S.; Unruh, T.; Demeshko, S.; Domenianni, L.; van
Leest, N.P.; Marquetand, P.; Schneck, F.; Würtele, C.; de Zwart, F.J. de Bruin, B.; González, L.; Vöhringer, P.; Schneider, S. Chem. Eur. J., 2021,
27 (68), 16978-16989.
[link]
261. How to prepare kinetically stable self-assembled Pt12L24
nanospheres circumventing kinetic traps
Bobylev, E.O.; Poole III, D.A.; de Bruin, B.; Reek, J.N.H. Chem.
Eur J. 2021, 49, 12667-12674.
[link]
260. A chromatography-free synthesis of meso-tetrakis(4-formyl-phenyl)porphyrin
and meso-tetrakis(3-formylphenyl)porphyrin: versatile
synthons in supramolecular and macromolecular chemistry
Mouarrawis, V. ; Mathew, S.; Meeus,
E.J.; de Bruin, B.*; Reek, J.N.H.* J. Porphyr.
Phthalocyanines, 2021, https://doi.org/10.1142/S1088424621500504.
[link]
259. Controlling the Activity of a Caged Cobalt–Porphyrin-Catalyst in Cyclopropanation Reactions with Peripheral Cage
Substituents
Mouarrawis, V.; Bobylev, E.O.; de Bruin, B.*; Reek, J.N.H.* Eur.
J. Inorg. Chem., 2021, 2890 –2898.
[link]
258. Revisiting the Electronic Structure of Cobalt-Porphyrin Nitrene and
Carbene Radicals with NEVPT2-CASSCF Calculations: Doublet versus Quartet Ground
States
Leest, N.P; de Bruin, B.* Inorg. Chem
2021, 60, 12, 8380–8387.
Featured Article. Most accessed
paper of the month, June 2021
[link] [ChemRxiv]
257. A Novel M8L6 Cubic Cage that Binds Tetrapyridyl Porphyrins; Cage and Solvent Effects in
Cobalt–porphyrin‐catalyzed Cyclopropanation
Reactions
Mouarrawis, V. ; Bobylev, E. ; de Bruin, B.*; Reek.
J.N.H.* Chem. Eur. J. 2021, 27, 8390–8397.
[link]
256. Selective formation of Pt12L24 nanospheres by
ligand design
Bobylev, E.O.; Poole III,
D.A.; de Bruin, B.; Reek, J.N.H. Chem. Sci. 2021, 12,
7696–7705.
[link]
255. Supramolecular Systems Containing B–N Frustrated Lewis Pairs of
Tris(pentafluorophenyl)borane and Triphenylamine
Derivatives
Chidchoba, P.; Jansen S. A. H.; Meskers, S. C. J.; Weyandt, E.; van Leest, N. P.; de Bruin, B.; Palman, A. R. A.; Vantomme, G.;
Meijer, E. W. Organic Materials
2021, 03(02), 174-183.
[link]
254. Pursuit of an Electron Deficient Titanium Nitride
Grant, L.N.; Bhunia, M.; Pinter, B.; Rebreyend,
C.; Carroll, M.E.; Carroll, P.J.; de Bruin, B.; Mindiola, D.J. Inorg. Chem 2021,
60, 8, 5635–5646.
[link]
253. Metrical oxidation states of 1,4-diazadiene (DAD) derived ligands
de Zwart, F.J.; Reus, B.;
Laporte, A.A.H.; Sinha, V.; de Bruin, B.* Inorg. Chem 2021,
60, 5, 3274–3281.
[link] [ChemRxiv]
252. Tellurium(II)/Tellurium(III)‐Catalyzed
Cross‐Dehydrogenative C−N Bond Formation
Cremer, C.; Goswami,
M.; Rank, C.K.; de Bruin, B.; Patureau, F.W. Angew. Chem.
Int. Ed. 2021, 60, 6451–6456.
[link]
251. Journal Open Access and Plan S: Solving Problems or Shifting
Burdens?
Kamerlin, S.C.; Allen, D.; de Bruin, B.; Deratt,
E.; Urdal, H. Development and Change, 2021, 52(3),
627–650. DOI: 10.1111/dech.12635.
[link]
250. Electrochemical Aziridination of Internal Alkenes with Primary
Amines
Ošeka, M.; Laudadio, G.; van Leest, N.P.; Dyga,
M.; Bartolomeu, A.de A.; Gooßen, L.J.; de Bruin, B.;
de Oliveira, K.T.; Noël, T. Chem 2021, 7, 255–266.
[link]
249. Catalytic Chemoselective Sulfimidation with an Electrophilic [CoIII(TAML)]‒-Nitrene
Radical Complex
van Leest, N.P.; van der Vlugt, J.I.;
de Bruin, B.* Chem. Eur. J. 2021, 27, 371–378.
‘Hot Paper’
[link] [ChemRxiv]
2020
248. Low-Valent
Anionic a-Diimine Iron Complexes: Synthesis, Characterization, and
Catalytic Hydroboration Studies
Maier, T.M.; Gawron, M.; Coburger, P.; Bodensteiner, M.; Wolf, R. van Leest, N.P.; de Bruin, B.; Demeshko, S.; Meyer, F. Inorg.
Chem. 2020, 59,
16035−16052.
[link]
247. To B or not to
B: Single-electron Transfer in Frustrated Lewis Pair Chemistry
Holtrop, F.; Jupp, A.R. ; Kooij, B. ; van Leest, N.P. ;
de Bruin, B.; Slootweg, J.C. Angew. Chem. Int. Ed. 2020, 59, 22210–22216.
‘Hot Paper’
[link] [ChemRxiv]
246. Role of the
ligand and activator in selective Cr−PNP ethene tri- and tetramerization
catalysts – a spectroscopic study
Venderbosch, B.; Wolzak, L.A.; Oudsen, J.-P.H.; de Bruin, B.; Korstanje,
T.J.; Tromp, M. ChemCatChem 2020,
10, 6212-6222.
[link]
245. A Platinum(II) Metallonitrene with a Triplet Ground State
Sun, J.; Abbenseth, J.; Verplancke, H.;
Diefenbach, M.; de Bruin, B.; Hunger, D.; Würtele,
C.; van Slageren, J.; Holthausen, M.C.; Schneider, S.
Nature Chem. 2020, 12, 1054–1059. DOI:
10.1038/s41557-020-0522-4.
[link] [ChemRxiv]
244. Ligand-Mediated Spin
State Changes in a Cobalt-Dipyrrin-Bisphenol Complex
van Leest,
N.P.; Stroek, W.; Siegler,
M.A.; van der Vlugt, J.I.; de Bruin, B.* Inorg. Chem. 2020, 59, 12903−12912
Among 3 most read IC papers of Aug.
2020
[link] [ChemRxiv]
243. Chiral-at-Ruthenium
Catalyst Does the Job: Access to Enantioenriched 2-lmidazolidinones
van Leest,
N.P.; van Vliet, K.M.; de Bruin, B.* Chem. 2020, 6 (8), 1851–1853.
[link]
242. Phosphorus Analogues of [Ni(bpy)2]:
Synthesis and Application in Carbon−Halogen Bond Activation
Leitl, J.; Coburger, P.; Scott, D. J.; Ziegler, C. G. P.; Hierlmeier, G.; Wolf, R.*; van Leest, N. P.; de Bruin, B.*; Hörner,
G.; Müller, C.* Inorg. Chem. 2020, 59, 9951–9961.
[link]
241. Electronically
Asynchronous Transition States for C–N Bond Formation by Electrophilic [CoIII(TAML)]-Nitrene Radical Complexes Involving
Substrate-to-Ligand Single-Electron Transfer and a Cobalt-Centered
Spin Shuttle
van Leest, N.
P.; Tepaske, M. A.; Venderbosch, B.; Oudsen, J.-P.; Tromp, M.; van der Vlugt, J. I.; de Bruin,
B.* ACS Catalysis
2020, 10, 7449-7463.
[link] [ChemRxiv]
240. Aggregation and
Degradation of White Phosphorus Mediated by 12 Valence Electron Nickel(0)
Fragments
Hierlmeier, G.;
Coburger, P.; van Leest, N.P.; de Bruin, B.; Wolf, R.
Angew. Chem. Int.
Ed. 2020, 59, 14148 –14153.
[link]
239. Catalytic
Synthesis of 8‐Membered Ring Compounds via Cobalt(III)‐Carbene
Radicals
Zhou, M.;
Lankelma, M.; van der Vlugt, J.I.; de Bruin, B.* Angew. Chem. Int. Ed. 2020, 59,
11073–11079.
[link] [ChemRxiv]
Highlighted in SynFacts
238. Photoinduced and
Thermal Single‐Electron Transfer to Generate Radicals from Frustrated
Lewis Pairs
Holtrop, F.; Jupp, A. R.; van Leest, N. P.; Dominguez,
M. P.; Williams, R. M.; Brouwer, A. M.; de Bruin, B.; Ehlers,
A. W.; Slootweg. J. C. Chem. Eur. J. 2020, 26, 9005–9011
[link]
237. An In-Depth
Mechanistic Study of Ru Catalysed Aqueous Methanol Dehydrogenation and
Prospects for Future Catalyst Design
Govindarajan,
N.; Sinha, V.; Trincado, M.; Grützmacher, H.; Meijer,
E. J.; de Bruin, B.* ChemCatChem 2020, 12, 2610–2621.
[link] [ChemRxiv]
236. Three-Coordinate
Rhodium Complexes in Low Oxidation States
Varela-Izquierdo,
V.; López, J. A.; de Bruin, B.; Tejel, C.; Ciriano,
M. A. Chem. Eur. J. 2020, 26, 3270–3274.
[link]
235. Copper-Catalyzed Oxidative Dehydrogenative Functionalization of
Alkanes to Allylic Esters
Mondal, R.; Chakraborty, G.; van Vliet, K.M.; van Leest, N.P.; de
Bruin, B.; Paul, N.D.; Inorg. Chim. Acta. 2020, 500, 119190.
[link]
234. Dioxazolones; Stable substrates for
the catalytic transfer of acyl nitrenes
Van Vliet,
K.M.; de Bruin, B.* ACS Catalysis 2020,
10, 4751–4769.
[link]
233. Investigating
the active species in a [(R-SN(H)S-R)CrCl3] ethene trimerization
system: mononuclear or dinuclear?
Venderbosch,
B.; Oudsen, J.-P. H.; Martin, D.J..; de Bruin, B.; Korstanje, T.J.; Tromp, M. ChemCatChem 2020, 12, 881–892.
[link]
232. Visible-light-induced
addition of carboxymethanide to styrene from
monochloroacetic acid
van Vliet, K.
M.; van Leeuwen, N. S.; Brouwer, A. M.; de Bruin, B.*; Beilstein J. Org. Chem. 2020,
16, 398–408. doi:10.3762/bjoc.16.38
[link]
231. Ligand Redox Non-Innocence
in [CoIII(TAML)]0/‒ Complexes Affects Nitrene Formation
van Leest,
N.P.; Tepaske, M.A.; Oudsen,
J.-P.H.; Venderbosch, B.; Rietdijk, N.R.; Siegler,
M.A.; Tromp, M.; van der Vlugt, J.I.*; de Bruin, B.* J. Am. Chem. Soc. 2020, 142, 552–563. DOI:
10.1021/jacs.9b11715.
[link] [ChemRxiv]
2019
230. Rhodium
Complexes in P−H Bond Activation Reactions
Varela-Izquierdo, V.;
Geer, A.M.; de Bruin, B.; López, J.A.; Ciriano, M.A.;
Tejel, C.; Chem.
Eur. J. 2019, 25, 15915–15928.
[link]
229. Rational
Redesign of a Regioselective Hydroformylation Catalyst for 3-Butenoic Acid by
Supramolecular Substrate Orientation
Bai, S.-T.; Sinha, V.;
Kluwer, A.M.; Linnebank, P.R.; Abiri, Z.; de Bruin,
B.; Reek, J.N.H.; ChemCatChem. 2019, 11, 5322–5329.
[link]
228. Cross-linking
polyethylene through carbenes
De
Zwart, F.J.; Bootsma, J.; de Bruin, B.* Science,
2019, 366 (6467), 800. DOI:
10.1126/science.aaz7612
[link] [Open
Access pdf] [Open
Access full text]
Invited Perspective
(Insights)
227. Phosphine Oxide
Based Supramolecular Ligands in the Rhodium-Catalyzed
Asymmetric Hydrogenation
Daubignard, J.;
Detz, R.J.; de Bruin, B.; Reek, J.N.H. Organometallics. 2019,
38, 3961–3969.
[link]
226. Steric Protection of Rhodium‐Nitridyl
Radical Species
Rebreyend,
C.; Mouarrawis, V.; Ziegler,
M. A.; van der Vlugt, J.I.; de Bruin, B.* Eur. J. Inorg. Chem. 2019, 4249–4255.
[link] [ChemRxiv]
225. Efficient Copper
Catalyzed Multi-component Synthesis of N-acyl
amidines via Acyl Nitrenes
van Vliet,
K.; Polak, L.; Siegler, M.; van der Vlugt, J.I.; Fonseca Guerra, C.; de Bruin, B.* J. Am. Chem. Soc. 2019, 141 (38), 15240-15249
[link] [ChemRxiv]
224. Origin of the
selectivity and activity in the Rhodium-catalyzed
asymmetric hydrogenation using supramolecular ligands
Daubignard, J.; Lutz, M.; Detz, R.; de Bruin, B.; Reek,
J.N.H. ACS Catalysis 2019, 9, 8, 7535-7547.
[link]
223. Cobalt-Catalyzed Hydrogenations via Olefin
Cobaltate and Hydride Intermediates
Sandl,
S.; Maier, T.; Leest, N.P.; Kröncke, S. Chakraborty,
U.; Demeshko, S.; Koszinowski,
K.; de Bruin, B.; Meyer, F.; Bodensteiner, M.; Herrmann, C.; Wolf, R.; Jacobi
von Wangelin. A. ACS Catalysis 2019, 9, 8, 7596-7606.
[link]
222. Effector responsive hydroformylation catalysis
Bai,
S.-T.; Sinha, V.; Kluwer, A.M.; Linnebank, P.R.;
Abiri, Z.; Dydio, P.; Lutz, M.; de Bruin, B.; Reek,
J.N.H. Chem. Sci., 2019, 10, 7389-7398.
[link]
221. [Co(TPP)]-Catalyzed Formation of
Substituted Piperidines
Lankelma, M.;
Olivares, A.M; de Bruin, B.* Chem. Eur. J. 2019, 25, 5658 –5663
[link] [ChemRxiv]
‘Hot Paper’
220. Uncatalysed Oxidative C‒H
Amination of 9,10-Dihydro-9-Heteroanthracenes: A Mechanistic Study
van Leest,
N.P. Grooten, L.; van der Vlugt, J.I. de Bruin, B.* Chem. Eur. J. 2019, 25, 5987 –5993.
[link] [ChemRxiv]
‘Hot Paper’
219. Interconversion of Phosphinyl Radical and Phosphinidene Complexes by Proton Coupled Electron Transfer
Abbenseth,
J.; Neben, M.C.; Delony, D.; Würtele,
C.; de Bruin, B.*; Schneider, S.* Angew. Chem. Int. Ed., 2019, 58, 6338–6341.
[link]
218. Iron-Catalyzed/Mediated C–N Bond
Formation: Competition between Substrate Amination and Ligand Amination
Sinha, S.; Sikari, R.; Sinha, V.; Jash, U.; Das, S.; Brandăo, P.; Demeshko, S.; Meyer, F.; de Bruin, B.; Paul, N.D. Inorg. Chem., 2019, 58, 1935–1948.
[link]
217. A low-valent dinuclear ruthenium diazadiene complex catalyzes the
oxidation of dihydrogen and reversible hydrogenation of quinones
Yang,
X.; Gianetti, T. L.; Wörle, M. D.; van Leest, N. P.;
de Bruin, B.; Grützmacher, H., Chemical Science, 2019, 10, 1117-1125.
[link]
2018
216. DFT Provides Insight into the Additive-Free Conversion of Aqueous
Methanol to Dihydrogen Catalyzed by [Ru(trop2dad)]:
Importance of the (Electronic) Flexibility of the Diazadiene
Moiety
Sinha,
V.; Trincado, M.; Grützmacher, H.*; de Bruin, B.* J. Am. Chem. Soc.,
2018, 140, 13103-13114.
[link]
215. Aqueous Phase Separation Behavior of
Highly Syndiotactic, High Molecular Weight Polymers with Densely Packed
Hydroxy-Containing Side Groups
Tromp, D.S.;
Lankelma, M.; de Valk, H.; de Josselin de Jong, E.;
de Bruin, B.* Macromolecules, 2018, 51, 7248-7256.
[link]
214. Aryldiazonium Salts as Nitrogen-Based Lewis acids: Facile Synthesis
of Tuneable Azophosphonium Salts
Habraken, E.R.M.; van Leest, N.P.; Hooijschuur,
P.; de Bruin, B.; Ehlers, A.W.; Lutz, M.; Slootweg,
J.C. Angew. Chem. Int. Ed, 2018, 57, 11929 –11933.
[link]
213. Radical-type Reactions Controlled by Cobalt: From Carbene Radical
Reactivity to the Catalytic Intermediacy of Reactive o-Quinodimethanes
te Grotenhuis, C.; de Bruin, B.* Synlett, 2018, 29, 2238-2250.
[link]
212. Synthesis, electronic structure and redox properties of the
diruthenium sandwich complexes [Cp*Ru(µ-C10H8)RuCp*]x (x = 0, 1+; Cp* = C5Me5;
C10H8 = naphthalene)
Herrmann, D.; Rödl, C.; de Bruin, B.; Hartl, F.; Wolf, R. Dalton Trans., 2018, 47, 11058-11069.
[link]
211. Reactivity of Rhodium(II) Amido / Rhodium(I) Aminyl
Complexes
Zhang, N.; Zhu, D.; Herbert, D. E.; van
Leest, N. P.; de Bruin, B.; Budzelaar, P.H.M. Inorg. Chim. Acta, 2018, 482, 709-716.
[link]
210. How Solvent Affects C-H Activation and Hydrogen Production Pathways
in Homogeneous Ru-Catalysed Methanol Dehydrogenation Reactions
Sinha, V.;
Govindarajan, N.*; de Bruin, B.*; Meijer, E.J. ACS Catalysis, 2018, 8, 6908–6913.
[link]
209. Pump-probe XAS investigation of the triplet state of Ir photosensitizers with chromenopyridinone
ligands
Smolentsev, G.; van Vliet, K.M.; Azzaroli, N.; van Bokhoven, J.; Brouwer, A.M.; de Bruin,
B.; Nachtegaal, M.; Tromp, M. Photochem. Photobiol. Sci., 2018, 17, 896–902.
[link]
208. Mechanism of the dehydrogenative
phenothiazination of phenols
Goswami, M.; Konkel, A.; Rahimi,
M.; Louillat-Habermeyer, M.-L.; Kelm,
H,; Jin, R.; de Bruin, B.*; Patureau, F.W.* Chem. Eur. J., 2018,
24, 11936–11943.
[link]
‘Hot Paper’; Frontispies
207. An Iridium(III/IV/V) Redox Series featuring a terminal Imido Complex
with Triplet Ground State
Kinauer, M.; Diefenbach, M.;
Bamberger, H.; Demeshko, S.; Reijerse,
E.J.; Volkmann, C.; Würtele, C.; van Slageren, J.; de Bruin, B.*; Holthausen, M.C.*; Schneider,
S.* Chemical Science, 2018,
9, 4325–4332.
[link]
206. [Co(MeTAA)]
Metalloradical Catalytic Route to Ketenes via
Carbonylation of Carbene Radicals
Chirila, A.; van Vliet, K.M.; Paul, N.D.; de
Bruin, B.* Eur. J. Inorg. Chem., 2018, 2251–2258.
[link]
‘VIP Paper’; Frontcover
205. Nickel-alkyl complexes with a
reactive PNC-pincer ligand
Jongbloed, L. S.; Vogt,
N.; Sandleben, A.; de Bruin, B.; Klein, A.; van der
Vlugt, J.I. Eur. J. Inorg. Chem., 2018, 2408–2418.
[link]
204. Porphyrin Co(III)-nitrene radical mediated pathway for synthesis of o-aminoazobenzenes
Goswami, M.; de Bruin, B.* Molecules, 2018, 23, 1052; doi:10.3390/molecules23051052
[link]
Special issue ‘Radical Chemistry’
203. Ligand- and Metal-Based Reactivity of
a Neutral Ruthenium Diolefin Diazadiene Complex; The
Innocent, the Guilty, and the Suspicious
Sinha, V.; Pribanic,
B.; de Bruin, B.*; Trincado, M.*; Grützmacher,
H.* Chem. Eur. J. 2018,
24, 5513–5521.
[link]
‘Hot Paper’; Frontcover;
Cover Profile
202. Catalytic Synthesis of Indolines via Hydrogen Atom Transfer to Cobalt(III)–Carbene
Radicals
Karns, A.S.; Goswami,
M.; de Bruin, B.* Chem. Eur. J., 2018,
24, 5253–5258.
[link]
Special Issue: ECOSTBio – Spin
States and Reactivity
201. Mechanistic investigations into the cyclopropanation of electron deficient alkenes with ethyl
diazoacetate using [Co(MeTAA)]
Chirila, A.; Brands,
M.B.; de Bruin, B.* Journal of Catalysis,
2018, 361, 347–360.
[link]
200. Catalytic dibenzocyclooctene
synthesis via cobalt(III)-carbene radical and ortho-quinodimethane
intermediates
te Grotenhuis, C.; van den Heuvel, N.;
van der Vlugt, J. I.; de Bruin, B.* Angew. Chem. Int. Ed., 2018, 57, 140–145.
Frontispies
[link]
199. Coordination of 3-methylindole-based
tripodal tetraphosphine ligands to iron(+II),
cobalt(+II) and nickel(+II) and investigations of their subsequent
two-electron-reduction
van de Watering, F.F.; Stroek, W.; van der Vlugt, J.I.; de Bruin, B.; Dzik, W.I.,
Reek, J.N.H. Eur. J. Inorg. Chem., 2018, 11, 1254–1265.
[link]
198. Application of anionic [Co(Cor)]- corrole complexes in
ring-closing C-H amination of aliphatic azides via nitrene radical intermediates
Goswami, M.; Geuijen,
P.; Reek, J.N.H.; de Bruin, B.* Eur. J. Inorg. Chem., 2018, 5, 617–626.
[link]
197. The Importance of the Reducing Agent in Direct
Reductive Heck Reactions
Raoufmoghaddam, S.; Mannathan,
S. Minnaard, A.; de Vries, H.; de Bruin, B.; Reek,
J.N.H. ChemCatChem, 2018, 10, 266–272.
[link]
2017
196. Electrocatalytic Azide
Oxidation Mediated by a Rh(PNP) Pincer Complex
Rebreyend, C.; Gloaguen, Y.; Lutz, M.;
van der Vlugt, J.I.; Siewert, I.; Schneider, S.*; de
Bruin, B.* Chem. Eur. J., 2017,
23, 17438–17443.
‘Hot Paper’;
Inside Front Cover
[link]
195. 3-Methylindole-Based Tripodal Tetraphosphine Ruthenium Complexes in N2
Coordination and Reduction and Formic Acid Dehydrogenation
van de Watering, F.F.; Heijtbrink, N.; van der Vlugt,
J.I.; Dzik, W.I.; de Bruin, B.*; Reek, J.N.H.* Inorganics 2017, 5(4), 73;
doi:10.3390/inorganics5040073.
[link]
194. Redox-Active Bis(phenolate)
N-Heterocyclic Carbene [OCO] Pincer Ligands Support Cobalt Electron Transfer
Series Spanning Four Oxidation States
Harris,
C.F.; Bayless, M.B.; van Leest, N.P.; Bruch, Q.J.; Livesay, B.N.; Bacsa, J.;
Hardcastle, K.I.; Shores, M.P.*; de Bruin, B.*; Soper, J.D.* Inorg. Chem., 2017, 56, 12421–12435.
[link]
193. Catalytic 1,2-Dihydronaphthalene and
E-Aryl-Diene Synthesis via CoIII-Carbene Radical and o‑Quinodimethane Intermediates
te Grotenhuis, C.; Das, B.G.; Kuijpers, P.F. Hageman,
W.; Trouwborst, M.; de Bruin, B.* Chemical Science, 2017,
8, 8221–8230.
[link]
192. Transition Metal-Free Cleavage of CO
Devillard, M.; de Bruin, B.; Siegler, M. A.; van der Vlugt, J.I., Chem.
Eur. J., 2017, 23, 13628–13632.
[link]
191. Metalloradical
Reactivity of Ru(+I) and Ru(0) Stabilized by an Indole-based Tripodal Tetraphosphine Ligand
van de
Watering, F.F.; van der Vlugt, J.I.;
Dzik, W.I.*; de Bruin, B.*; Reek, J.N.H.*, Chem. Eur. J., 2017, 23, 12709–12713.
‘Hot Paper’.
[link]
190. Rational Design of Supramolecular
Catalysts for the Rhodium-Catalyzed Asymmetric Hydrogenation Reaction
Daubignard, J.;
Detz, R.; Jans, A.C.H.; de Bruin, B.; Reek, J.N.H. Angew. Chem. Int. Ed.,
2017, 56, 13056–13060.
[link]
189. Nitrene Radical Intermediates
in Catalytic Synthesis
Kuijpers,
P.F.; van der Vlugt, J. I.; Schneider, S.; de Bruin, B.*, Chem. Eur. J., 2017, 56, 13819–13829.
Concept paper. Top 10 most accessed papers 10/2017
[link]
188. On the Balance Between Metal and
Ligand Reduction in Diiminepyridine Complexes of Ti
Rahimi, N.; de Bruin, B.; Budzelaar,
P.H.M., Organometallics, 2017, 36, 3189–3198.
Front cover
[link]
187. Electronic Structure and Magnetic
Anisotropy of an Unsaturated 15-Valence-Electron Cyclopentadienyl Iron(I)
Complex
Chakraborty, U.; Demeshko, S.; Meyer, F.*; Rebreyend,
C.; de Bruin, B.*; Atanasov, M.*; Neese, F.; Mühldorf,
B.; Wolf, R.*, Angew. Chem. Int. Ed., 2017, 56, 7995–7999.
[link]
186. N-Atom Transfer via Thermal or
Photolytic Activation of a Co-Azido Complex with a PNP Pincer Ligand
Vreeken, V.; Baij,
L.; de Bruin, B.; Siegler, M.A.; van der Vlugt, J.I. Dalton, 2017,46, 7145–7149.
[link]
185. Selective P4 Activation
by a Highly-Reduced Cobaltate: Synthesis of Dicobalt Tetraphosphido Complexes
Pelties, S.; Maier, T.;
Herrmann, D.; de Bruin, B.; Rebreyend, C.; Gärtner,
S.; Shen-derovich, I.G.; Wolf, R., Chem. Eur. J., 2017, 23, 6094–6102.
[link]
184. Nitrene-radical approach to
Saturated Heterocycles; Cobalt Porphyrin Catalysed
Intramolecular Ring-Closing C-H Amination of Aliphatic Azides
Kuijpers, P.F.; Tiekink,
M. J.; Breukelaar, W.B.; Broere, D.L.J.; van Leest,
N.P.; van der Vlugt, J.I.; Reek, J.N.H.; de Bruin, B.*. Chem. Eur. J. 2017, 23, 7945–7952.
‘Very Important Paper’; Inside Front Cover.
[link]
183. A Stable Aminyl
Radical Coordinated to Cobalt
Rodríguez-Lugo, R.E.; de
Bruin, B.*, Trincado, M.; Grützmacher, H.*, Chem. Eur. J., 2017, 23, 6795–6802
‘Hot Paper’; Front cover
[link]
182. Catalytic Synthesis of
N-Heterocycles via Direct C(sp3)-H Amination using an Air-stable Iron(III)
Species with a Redox-Active Ligand
Bagh, B.; Broere, D.L.J.;
Sinha, V.; Kuijpers, P.F.; van Leest, N.P.; de Bruin, B.*; Demeshko,
S.; Siegler, M.A. van der Vlugt, J.I.*, J. Am. Chem. Soc., 2017, 139, 5117–5124.
[link]
181. Homogeneously Catalysed
Conversion of Aqueous Formaldehyde to H2 and Carbonate
Trincado, M.*; Sinha, V.; Rodriguez-Lugo,
R.E.; Pribanic, B.; de Bruin, B.*; Grützmacher, H.*; Nature
Communications, 2017, 8, 14990. DOI:
10.1038/ncomms14990.
[link]
180. Difluorocarbene transfer from a
cobalt complex to an electron-deficient alkene
Goswami, M.; de Bruin, B.*; Dzik, W.I.*, Chem. Comm., 2017, 53, 4382–4385.
[link]
179. Diastereoselective Radical-Type Cyclopropanation of Electron Deficient Alkenes Mediated by
the Highly Active [Co(MeTAA)] Catalyst
Chirila, A.; Das, B.G.;
Paul, N.D.; de Bruin, B.*; ChemCatChem, 2017,
9, 1413–1421.
[link]
Front cover.
178. Metal Catalysed
Azidation of Organic Molecules
Goswami, M.; de Bruin, B.*; Eur. J. Org. Chem., 2017, 1152–1176.
[link]
Review. Top 10 most accessed papers (November 2017)
2016
177. Hydroformylation of 1-Octene Mediated by the Cobalt Complex [CoH(dchpf)(CO)2]
Kluwer, A.M.*; Krafft, M.J.; Hartenbach, I.; de Bruin, B.*; Kaim, W.*, Topics in Catalysis,
2016, 59 (19-20), 1787–1792. doi:10.1007/s11244-016-0699-3.
[link]
Invited
Contribution. Special issue ISHHC17 conference.
176. Accessing the CpArNi(I)
Synthon: Reactions with N-heterocyclic Carbenes, TEMPO, Sulfur, and Selenium
Chakraborty, U.; Urban, F.; Mühldorf,
B.; de Bruin, B.; van Velzen, N.; Harder, S.; Wolf, R. Organometallics, 2016, 35, 1624–1631.
[link]
175. Selective Co-encapsulation Inside a
M6L4 Cage
Leenders, S.H.A.M.; Becker, R.;
Kumpulainen, T.; de Bruin, B.; Sawada, T.; Kato, T.; Fujita, M.; Reek, J.N.H. Chem. Eur. J., 2016, 43, 15468–15474.
[link]
174. Reactivity of a ruthenium-carbonyl
complex in the methanol dehydrogenation reaction
van de Watering, F.F.; Lutz,
M.; Dzik, W. I.; de Bruin, B.; Reek, J. N. H., ChemCatChem, 2016, 8,
2752–2756.
[link]
173. Localized Mixed Valence and
Redox-Activity within a Triazole-Bridged Dinucleating
Ligand upon Coordination to Palladium
Broere, D.L.J.; Plessius,
R.; Tory, J.; Demeshko, S.; de Bruin, B.; Siegler,
M.A.; Hartl, F.; van der Vlugt, J. I., Chem. Eur. J., 2016, 22, 13965–13975.
[link]
172. Reversible Redox Chemistry and Catalytic Reactivity of a
Paramagnetic Pd Complex bearing a Redox-Active NNO Pincer Ligand
Broere, D.L.J.; van Leest, N.P.; de Bruin, B.; Siegler, M.A.; van der Vlugt, J.I. Inorg. Chem., 2016, 55, 8603–8611.
[link]
171. Deprotonation Induced Ligand
Oxidation in a NiII Complex of a Redox
Non-innocent N1-(2-aminophenyl)benzene-1,2-diamine and its Use in Catalytic
Alcohol Oxidation
Sikari, R.; Sinha, S.; Jash,
U.; Das, S.; Brandăo, P.; de Bruin, B.; Paul, N.D. Inorg. Chem., 2016, 55, 6114–6123.
[link]
170. CoIII-Carbene Radical Approach to
Substituted 1H-Indenes
Das, B.G.; Chirila, A.; Tromp, M.;
Reek, J.N.H; de Bruin, B.*, J. Am. Chem.
Soc., 2016, 138, 8968−8975.
[link]
169. A Self-Assembled Molecular Cage for
Size-Selective Epoxidation Reactions in Aqueous Media
Kuijpers, P.F.; Otte, M.; Dürr, M.;
Ivanović-Burmazović, I.; Reek, J.N.H.; de
Bruin, B.* ACS Catalysis, 2016,
6, 3106–3112.
Virtual issue ‘Catalysis in the
Netherlands’
[link]
168. [CpArNi{Ga(nacnac)}]:An Open-Shell Nickel(I)
Complex Supported by a Gallium(I) Carbenoid (CpAr = C5(C6H4-4-Et)5,
nacnac = HC[C(Me)N-(C6H3)-2,6-iPr2]2)
Chakraborty, U.; Mühldorf,
B.; van Velzen, N.; de Bruin, B.; Harder, S.; Wolf, R. Inorg. Chem, 2016, 55, 3075–3078.
[link]
167. Reactivity of Me-pma Rh(I)- and Ir(I)-complexes upon deprotonation and their application in
catalytic carbene carbonylation reactions
Tang, Z.; Tejel,
C.; Martinez de Sarasa Buchaca, M.; Lutz, M.; van der
Vlugt, J.I.; de Bruin, B.,* Eur. J. Inorg. Chem, 2016, 7, 963-974.
[link]
166. Reversible cyclometalation at RhI as Motif for Metal-Ligand Bifunctional Bond Activation
and Base-free Formic Acid Dehydrogenation
Jongbloed, L.S.; de Bruin, B.; Reek,
J.N.H.; Lutz, M.; van der Vlugt, J.I., Catal. Sci.
Technol., 2016, 6, 1320-1327.
[link]
165. Nucleophilicity and P−C Bond Formation Reactions of a Terminal
Phosphanido Iridium Complex
Serrano, A.L.; Casado, M.A.; Ciriano, M.A.; de Bruin, B.; López,
J.A.; Tejel, C.; Inorg.
Chem., 2016, 55, 828–839.
[link]
164. Porphyrin Cobalt(III) “Nitrene Radical” Reactivity; Hydrogen Atom
Transfer from Ortho-YH Substituents to the Nitrene Moiety of
Cobalt-Bound Aryl Nitrene Intermediates (Y = O, NH)
Goswami, M.; Rebreyend, C.;
de Bruin, B. Molecules, 2016, 21, 242–257.
[link]
2015
163. Hydrogenation of Carboxylic Acids
with a Homogeneous Cobalt Catalyst
Korstanje, T.J.;
van der Vlugt, J.I.; Elsevier, C.J.*; de Bruin, B.*, Science, 2015, 350 (6258), 298–302. DOI: 10.1126/science.aaa8938
[link]
SCIENCE
Free access: [Abstract] [Reprint] [Full text]
162. [Ni(cod)][Al(ORF)4],
a Source for Naked Ni(I) Chemistry
Schwab,
M.M.; Himmel, D.; Kacprzak, S.; Kratzert, D.; Radtke,
V.; Weis, P.; Ray, K.; Scheidt, E.-W.; Scherer, W.; de Bruin, B.; Weber, S.; Krossing, I., Angew. Chem. Int.
Ed., 2015, 54, 14706–14709.
[link]
‘Hot Paper’.
161. Rhodium Catalysed Conversion of Carbenes into Ketenes and Ketene
Imines using PNN Pincer Complexes
Tang, Z.; Mandal,
S.; Paul, N. D.; Lutz, M.; Li, P.; van der Vlugt, J.
I.; de Bruin, B.*, Org. Chem.
Front., 2015, 2,
1561–1577.
[link]
Themed Collection ‘Carbenes for Today’. RSC Gold-for-Gold Open Access
160. Photo- and Thermal-isomerization of (TP)Fe(CO)Cl2 [TP =
Bis(2-diphenylphosphinophenyl)-phenylphosphine]
Li, P.; de Bruin, B.; Reek, J.N.H.;
Dzik, W.I., Organometallics, 2015, 34, 5009–5014.
[link]
159. Low-Valent Iron-Mono-Diazadiene Compounds:
Electronic Structure and Catalytic Application
Lichtenberg,
C.; Adelhardt, M.; Gianetti,
T.; Meyer, K.; de Bruin, B.; Grützmacher, H., ACS Catal., 2015,
5, 6230–6240.
[link]
158. Homolytic N–H Activation of Ammonia: Hydrogen
transfer of Parent Iridium Ammine, Amide, Imide, and Nitride Species
Scheibel,
M.G.; Abbenseth, J.; Kinauer, M.; Heinemann, F. W.; Würtele, C.; de Bruin, B.*; Schneider, S.*, Inorg. Chem., 2015, 54, 9290–9302.
Forum Article.
[link]
157. Low-Valent Iron: an Fe(I) Ate Compound as a Building Block for a
Linear Trinuclear Fe Cluster
Lichtenberg, C.; Viciu, L.; Vogt, M.; Rodríguez-Lugo, R. E.; Adelhardt, M.;
Sutter, J.; Khusniyarov, M. M.; Meyer, K.; de Bruin,
B.; Grützmacher, H., Chem. Commun., 2015, 51, 13890–13893.
[link]
156. Dynamic Ligand
Reactivity in a Rhodium Pincer Complex
Tang, Z.; Otten, E.;
Reek, J.N.H.; van der Vlugt, J.I.*; de Bruin, B.*, Chem. Eur. J., 2015, 21, 12683–12693.
‘Hot Paper’. Front Cover. Cover Profile.
[link]
155. EPR Spectroscopy as a Tool in
Homogeneous Catalysis Research
Goswami,
M.; Chirila, A.; Rebreyend, C.; de Bruin, B.*, Topics in Catalysis, 2015,
58 (12-13), 719–750. DOI:
10.1007/s11244-015-0414-9.
Invited Review. Special issue on EPR
spectroscopy in Catalysis.
Open Access.
[link]
154. Pd-Catalyzed Z-Selective Semihydrogenation of Alkynes: Determining the Type of
Active Species
Drost,
R.M.; Rosar, V.; Dalla Marta, S.; Lutz, M.; Demitri, N.; Milani, B.; de Bruin,
B.; Elsevier, C.J., ChemCatChem, 2015, 7, 2095–2107.
[link]
153. Metalloradical-Catalyzed Selective 1,2-Rh-H
Insertion into Aliphatic Carbon-Carbon Bond of Cyclooctane
Chan,
Y.W.; de Bruin, B.*; Chan, K.S.*, Organometallics,
2015, 34, 2849–2857.
[link]
152. C-H Activation of Benzene by a
Photoactivated NiII(azide)
– Formation of a Transient Nickel Nitrido Complex
Vreeken, V.; Siegler, M.A.; de Bruin, B.; Reek, J.N.H.; Lutz, M.; van der Vlugt, J.I., Angew. Chem. Int. Ed., 2015, 54, 7055–7059.
[link]
151. Low-Valent Iron(I) Amido Olefin Complexes as Promotors for
Dehydrogenation Reactions
Lichtenberg,
C.*; Viciu, L.; Adelhardt,
M.; Sutter, J.; Meyer, K.; de Bruin, B.*; Grützmacher, H.* Angew. Chem. Int. Ed., 2015, 54, 5766–5771.
[link]
150. A comparison of the full catalytic
cycle of hydroformylation mediated by mono- and bisligated
triphenylphosphine-rhodium complexes by DFT
Jacobs, I.;
de Bruin, B.*; Reek, J.N.H.* ChemCatChem, 2015,
11, 1708–1718.
[link]
149. Characterization of Porphyrin-Co(III)-‘Nitrene
radical’ species relevant in catalytic nitrene transfer reactions
Goswami,
M.; Lyaskovskyy, V.; Domingos, S.R.; Buma, W.J.; Woutersen, S.; Troeppner, O.;
Ivanović-Burmazović, I.; Lu, H.; Cui, X.;
Zhang, X.P.*; Reijerse, E.J.; DeBeer, S.; van Schooneveld, M.M.; Pfaff, F. F.; Ray, K.; de Bruin, B.*, J. Am. Chem. Soc., 2015,
137, 5468−5479.
[link]
148. Dinuclear Palladium Complexes with Two
Ligand-Centered Radicals and a Single Bridging Ligand: Subtle Tuning of
Magnetic Properties
Broere,
D.L.J.; Demeshko, S.; de Bruin, B.; Pidko, E.A. Reek, J.N.H; Siegler, M.A.; Lutz, M.; van der Vlugt, J.I., Chem.
Eur. J., 2015, 21, 5879–5886.
[link]
147. Facile Synthesis and Versatile Reactivity of an
Unusual Cyclometalated RhI
Pincer Complex
Jongbloed,
L.S.; de Bruin, B.; Reek, J.N.H; Lutz, M.; van der
Vlugt, J.I. Chem. Eur. J., 2015, 21, 7297–7305.
[link]
146. Catalytic Synthesis of 2H-Chromenes
Majumdar,
N.; Paul, N.D.; Mandal, S.; de Bruin, B.*; Wulff, W.D.*, ACS Catalysis, 2015, 5, 2329−2366.
Invited Review.
[link]
145. A Mechanistic Study of Direct
Activation of Allylic Alcohols in Palladium Catalysed
Amination Reactions
Gumrukcu, Y.;
de Bruin, B.*; Reek, J.N.H*, Catalysts, 2015,
5, 349-365.
Invited
Paper for Special Issue: "Feature Papers to Celebrate the Landmarks of
Catalysts"
[link]
144. PdII(allyl)
Histidylidene Complexes and their Application in
Z-selective Transfer Semi-hydrogenation of Alkynes
Drost, R.M.;
Broere, D.L.J.; Hoogenboom, J.; de Baan, S.N.; Lutz,
M.; de Bruin, B.; Elsevier, C.J.; Eur. J. Inorg. Chem., 2015, 6, 982–996.
[link]
143. Novel Tetracobalt Cluster Compounds for
Electrocatalytic Proton Reduction: Syntheses, Structures, and Reactivity
Li, P.; Zaffaroni, R.; de Bruin, B.; Reek, J.N.H.; Chem. Eur. J., 2015,
10, 4027–4038.
[link]
142. Reactivity of dinitrogen bound to mid- and late
transition metal centers
Khoenkhoen, N.;
de Bruin, B.; Reek, J. N. H.; Dzik, W. I.; Eur. J. Inorg. Chem., 2015, 4, 567–598.
Front Cover
[link]
141. A Well-defined BisMETAMORPhos
PdI-PdI complex: Synthesis,
Structural Characterization and
Reactivity
Oldenhof, S.;
Lutz, M.; de Bruin, B.; van der Vlugt, J. I.; Reek,
J. N. H.; Organometallics, 2015, 33, 7293–7298.
[link]
140. Redox-Active Ligand-Induced Homolytic Bond Activation
Broere,
D.L.J.; Metz, L.L. de Bruin, B.; Reek, J.N.H.; Siegler, M.A.; van der Vlugt, J.I.; Angew. Chem. Int. Ed.,
2015, 5, 1516–1520.
[link]
139. Dehydrogenation of Formic Acid by Ir-bisMETA-MORPhos
Complexes: Experimental and Computational Insight in the Role of a Cooperative
Ligand
Oldenhof, S.; Lutz, M.; de Bruin, B.; van
der Vlugt, J.I.; Reek, J.N.H.; Chemical Science., 2015, 6, 1027–1034.
[link]
138. Transition Metal Catalysis in
Confined Spaces
Leenders,
S.H.A.M.; Gramage-Doria, R. de Bruin, B.; Reek,
J.N.H. Chem. Soc. Rev., 2015, 44, 433–448.
[link]
137. Terminal Phosphanido Rhodium Complexes
Mediating P-P and P-C Bond Formation
Geer,
A.M.; Serrano, A.L.; de Bruin, B.; Ciriano, M.A.; Tejel, C.; Angew. Chem. Int. Ed.,
2015, 2, 472–475
[link]
136. Photolytic N2 Splitting:
A Road to Sustainable NH3 Production?
Rebreyend,
C.; de Bruin, B.* Angew. Chem. Int.
Ed., 2015, 1, 42–44.
[link]
2014
135. Dehydrative cross-coupling reactions
of allylic alcohols with olefins
Gumrukcu, Y.; de
Bruin, B.*; Reek, J.N.H.* Chem. Eur. J., 2014, 20, 10905–10909.
[link]
Inside Cover
134. Intramolecular Redox-Active
Ligand-to-Substrate Single Electron Transfer: Radical Reactivity with a
Palladium(II) Complex
Broere,
D.; de Bruin, B.; Reek, J.N.H.; Lutz, M.; Dechert, S.; van der Vlugt, J.I.; J. Am.
Chem. Soc., 2014, 136, 11574−11577.
[link]
Front Cover
133. Direct Probing of Photo-induced
Electron Transfer in a Self-assembled Biomimetic [2Fe2S]-Hydrogenase Complex
using Ultrafast Vibrational Spectroscopy
Li,
P.; Amirjalayer, S.; Hartl, F.; Lutz, M.; de Bruin,
B.; Becker, R.; Woutersen, S.; Reek, J.N.H.; Inorg. Chem. 2014, 53, 5373–5383.
[link]
ACS Editors’ Choice
132. Selective P4 activation
by an organometallic nickel(I) radical: formation of a dinuclear
nickel(II) tetraphosphide and related di- and trichalcogenides
Pelties, S.; Herrmann, D. de Bruin, B.; Hartl,
F.; Wolf, R.; Chem. Commun., 2014, 50, 7014–7016.
[link]
131. Charge-Delocalized κ2‑C,N‑NHC-Amine
Complexes of Rhodium, Iridium, and Ruthenium
Jansen, E.; Lutz, M.; de Bruin, B.; Elsevier, C.J.; Organometallics, 2014, 33, 2853–2861.
[link]
130. Beyond Classical Reactivity
Patterns: Hydroformylation of Vinyl and Allyl Arenes to Valuable β- and
γ-Aldehyde Inter-mediates using Supramolecular Catalysis
Dydio, P.; Detz, R.J.; de Bruin, B.; Reek, J.N.H.; J. Am. Chem. Soc.,
2014, 136,
8418–8429.
[link]
129. An Isolated ‘Nitridyl-Radical’
Bridged {Rh(N•)Rh} Complex
Gloaguen, Y.; Rebreyend, C.; Lutz, M.;
Kumar, P.; Huber, M.; van der Vlugt, J.I.;
Schneider, S.*; de Bruin, B.*; Angew. Chem. Int. Ed., 2014, 53, 6814–6818.
[link]
‘Hot Paper’. Inside Front Cover
128. Computed Propagation and Termination
Steps in [(cycloocta-2,6-dien-1-yl)RhIII(polymeryl)]+ Catalyzed Carbene Polymerization
Reactions
Walters,
A.J.C.; Reek, J.N.H.; de Bruin, B.*; ACS Catalysis, 2014, 4, 1376–1389.
[link]
127. Encapsulated Cobalt–Porphyrin as
Catalyst for Size-Selective Radical-type Cyclopropanation
Reactions
Otte,
M.; Kuijpers, P.F.; Troeppner, O.; Ivanović-Burmazović, I.; Reek, J.N.H.; de Bruin, B.*; Chem. Eur. J., 2014, 20, 4880–4884.
[link]
126. Convenient transfer
semi-hydrogenation methodology for alkynes using a PdII-NHC
precatalyst
Drost, R.M.;
Bouwens, T.; van Leest, N.P.; de Bruin, B.; Elsevier, C.J.; ACS Catalysis, 2014,
4, 1349–1357.
[link]
125. H-bond Assistance in Palladium Catalysed Direct Activation of Allylic Alcohols
Y. Gumrukcu, B. de Bruin, J.N.H. Reek, ChemSusChem, 2014, 7, 890–896.
[link]
124. Amplified vibrational circular dichroism as a
probe of local biomolecular structure
Domingos, S.R.; Huerta-Viga, A.; Baij, L.;
Amirjalayer, S.; Dunnebier,
D.; Finger, M.; Walters, A.J.C.; Nafie, L.; de Bruin, B.*; Buma, W.
J.*; Woutersen, S.*.; J. Am. Chem. Soc., 2014, 136, 3530–3535.
[link]
123. A Metalloradical
Approach to 2H-Chromenes
Paul,
N.D.; Mandal, S. Otte, M. Cui. X. Zhang, X.P.; de Bruin, B.*, J. Am. Chem. Soc., 2014, 136, 1090–1096.
[link]
JACS Image
Challenge
122. Visible-light promoted N–H bond activations by
an organo-germanium corrole complex: reactivity and
mechanistic studies
Fang,
H.; Ling, Z.; Lang, K.; Brothers, P.J.; de Bruin, B.*; Fu, X.*; Chemical Science, 2014, 5, 916-921.
[link]
2013
121. Exchanging conformations of a hydroformylation
catalyst structurally characterized using two-dimensional vibrational
spectroscopy
Panman, M.R.; Vos, J.; Bocokić,
V.; Bellini, R.; de Bruin, B; Reek, J.N.H.; Woutersen.
S.; Inorganic Chemistry, 2013, 52, 14294−14298.
[link]
120. Diolefin Diamide Rhodium(I) Complex
and Its one Electron Oxidation Resulting in a 2 center 3 electron
Rhodium-Nitrogen bond
Rosenthal, A.J.; Vogt,
M.; de Bruin, B.*, Grützmacher, H.*.; Eur. J. Inorg. Chem., 2013, 2013, 34, 5831–5835.
[link]
119. Synthesis and Reactivity of a
Transient, Terminal Nitrido Complex of Rhodium
Scheibel,
M.G.; Wu, Y.; Stückl, A.C.; Krause, L.; Carl, E.; Stalke, D; de Bruin, B.*;
Schneider, S.*, J. Am. Chem. Soc., 2013, 135, 17719–17722.
[link]
118. Nitrogen-Centred
Ligand Radical Complexes; Classification, Spectroscopic Features, Reactivity
and Catalytic Applications
Olivos
Suarez, A.I.; Lyaskovskyy, V.; Reek, J.N.H.; van der Vlugt, J.I.; de Bruin, B.*; Angew. Chem. Int. Ed., 2013, 52, 12510–12529.
[link]
117. Synthesis and Electronic Structure
of Heteroleptic, Naphthalene-Bridged Sandwich
Complexes [Cp'Fe(μ-C10H8)MCp*]x (x = 0, +1; M = Fe, Ru; Cp' = η5-C5H2-1,2,4-tBu3;
Cp* = η5-C5Me5)
Malberg,
J.; Lupton, E.; Schnöckelborg, E.-M.; de Bruin, B.;
Sutter, J.; Meyer, K.; Hartl, F; Wolf, R.; Organometallics,
2013, 32, 6040–6052.
[link]
116. Ligand Effects on the Hydrogenation
of Biomass Inspired Substrates with Bifunctional NHC Ru, Ir
and Rh Complexes
Jansen, E.;
Jongbloed, L.S.; Tromp, D.S.; Lutz, M.; de Bruin, B.;
Elsevier. C.J.;
ChemSusChem,
2013, 9, 1737–1744.
[link]
115. Carbene Radicals in Cobalt(II)
Porphyrin-Catalysed Carbene Carbonylation Reactions;
A Catalytic Approach to Ketenes
Paul,
N.D.; Chirila, A.; Lu, H.; Zhang, X.P.*; de Bruin,
B.*; Chem. Eur. J., 2013,
19, 12953–12958.
[link]
114. Binuclear cooperative catalysts in
hydrogenation and hydroformylation of olefins
Hetterscheid, D.G.H.; Chikkali,
S.H.; de Bruin, B.; Reek, J.N.H.; ChemCatChem., 2013,
10, 2785–2793.
[link]
113. Encapsulation of Metallo-Porphyrins
in a Self-Assembled Cubic M8L6 Cage – A new Molecular
Flask for Cobalt-Porphyrin Catalyzed Radical-type Reactions
Otte,
M.; Kuijpers, P. F.; Troeppner, O.; Ivanović-Burmazović, I.; Reek, J.N.H.; de Bruin, B.*; Chem. Eur. J., 2013, 19, 10170–10178.
[link]
Back Cover.
112. On the ‘Tertiary Structure’ of
Poly-Carbenes; Self-assembly of sp3-Carbon Based Polymers into
Liquid-Crystalline Aggregates
Franssen,
N.M.G.; Ensing, B.; Hegde, M.; Dingemans, T.; Norder,
B.; Picken, S. J.; Alberda van Ekenstein, G.O.R.; van
Eck, E.; Elemans, J.A.A.W.; Vis, M; Reek, J.N.H.; de
Bruin, B.*; Chem. Eur. J., 2013,
19, 11577–11589.
[link]
Front Cover.
Highlighted on ChemistryViews
website:
www.chemistryviews.org/details/ezine/5018151/sp3-Carbon-Based_Liquid_Crystals.html
111. Bioinspired non-heme iron complexes
derived from an extended series of N,N,O-ligated BAIP ligands
Marcel
A. H. Moelands, M.A.H.; Nijsse, S.; de Bruin, B.;
Lutz, M.; Spek, A.L.; Klein Gebbink, R.J.M.; Inorg. Chem., 2013, 52, 7394–7410.
[link]
110. Reductive Elimination at an Orthometalated
IrIII Hydride bearing a Tripodal Tetraphosphorus Ligand
Gloaguen, Y.;
Jongens, L.M.; Lutz, M.; Reek, J. N. H.; de Bruin,
B.; van der Vlugt, J. I.; Organometallics, 2013, 32, 4284–4291.
[link]
109. Base-Free Production of H2
by Dehydrogenation of Formic Acid using an Iridium-bisMETAMORPhos
Complex
Oldenhof, S.; de
Bruin, B.; Lutz, M.; Siegler, M. Patureau, F.W.; van
der Vlugt, J.I.; Reek, J.N.H.; Chem. Eur. J., 2013,19, 11507–11511.
[link]
108. Synthesis of Functional ‘Polyolefins’: State of
the Art and Remaining Challenges
Franssen,
N.M.G.; Reek, J.N.H; de Bruin, B.*; Chem. Soc. Rev., 2013, 42, 5809-5832.
[link]
107. A different Route to Functional
Polyolefins: Olefin-Carbene Copolymerisation
Franssen,
N.M.G.; Reek, J.N.H; de Bruin, B.*; Dalton
Trans., 2013, 42, 9058-9068.
[link]
‘Hot Paper’. Inside Front Cover.
106. Propagation & Termination Steps in Rh-mediated
Carbene Polymerisation using Diazomethane
Franssen,
N.M.G.; Finger, M.; Reek, J.N.H; de Bruin, B.*; Dalton Trans., 2013, 42, 4139-4152
[link]
Inside Front Cover.
105. Catalyst Recycling via Specific
Non-Covalent Adsorption on Modified Silicas
Kluwer,
A.M.; Simons, C.; Knijnenburg, Q.; van der Vlugt, J.I.; de Bruin, B.; Reek, J.N.H.; Dalton Trans., 2013, 42, 3609-3616.
[link]
104. Open-Shell First-Row Transition
Metal Polyhydride Complexes Based on the fac-[RuH3(PR3)3]
Building Block
Plois, M.; Hujo, W.; Grimme, S.; Schwickert, C.; Bill, E.; de Bruin, B.; Pöttgen, R.; Wolf,
R.; Angew. Chem. Int.
Ed., 2013,
52, 1314 –1318.
[link]
103. Reactivity of a Mononuclear IrI Species Bearing a Terminal Phosphido Fragment Embedded in a Triphosphorus
Ligand
Gloaguen, Y.; Jacobs, W.; de Bruin, B.;
Lutz, M.; van der Vlugt, J.I.; Inorg. Chem., 2013, 52, 1682−1684.
[link]
102. Dibenzo[b,f]phosphepines: Novel Phosphane–Olefin
Ligands for Transition Metals
Lyaskovskyy, V.; van Dijk-Moes, R.J.A; Burck,
S.; Dzik, W.I.; Lutz, M.; Ehlers, A.W.; Slootweg,
J.C.; de Bruin, B.*, Lammertsma, K.* Organometallics, 2013, 32, 363–373.
[link]
Front Cover.
2012
101. Rh-Mediated C1-Polymerization: Copolymers from Diazoesters
and Sulfoxonium ylides
Olivos Suarez, A.I.;
del Río, M.P.; Remerie, K.; Reek, J.N.H.; de Bruin,
B.*; ACS Catalysis, 2012,
2, 2046–2059.
[link]
100. Unraveling the Electronic
Structures of Low-valent Naphthalene and Anthracene Iron Complexes: X-ray,
Spectroscopic and DFT Studies
Schnöckelborg,E.-M.; Khusniyarov,
M.M.; de Bruin, B.; Hartl, F.; Langer, T.; Eul, M; Schulz, S.; Pöttgen, R.; Wolf, R.; Inorg.
Chem., 2012, 51, 6719–6730.
[link]
99. Closed-Shell and Open-Shell Square-Planar Iridium Nitrido Complexes
Scheibel, M.G.;
Askevold, B.; Heinemann, F.; Reijerse, E.J.; de
Bruin, B.*; Schneider, S.*, Nature
Chemistry, 2012, 4, 552–558.
[link]
98. Chromatographic Examination of the Chemical
Composition and Sequence Distribution of Copolymers from Ethyl and Benzyl
Diazoacetate
Reingruber,
E.M.; Chojnacka, A.; Jellema, E.; de Bruin, B.; Buchberger, W.; Schoenmakers, P.J.; Journal
of Chromatography A, 2012, 1255, 259-266.
[link]
97. Controlled Synthesis of Functional Copolymers with Blocky
Architectures via Carbene Polymerization
Franssen,
N.M.G.; Remerie, K.; Macko, T.; Reek, J.N.H.; de
Bruin, B.*; Macromolecules, 2012, 45, 3711–3721
[link]
Highlighted in SynFacts:
DOI: 10.1055/s-0032-1317085.
96. Stereospecific Carbene Polymerisation with Oxygenated Rh(diene)
Species
Walters,
A.J.C.; Troeppner, O.; Ivanović-Burmazović, I.; Tejel, C.;
del Río, M.P.; Reek, J.N.H.; de Bruin, B.*; Angew. Chem. Int. Ed., 2012, 51, 5157-5161.
[link]
95. Highly selective asymmetric Rh-catalyzed hydroformylation
of heterocyclic olefins
Chikkali, S.H.;
Bellini,, R.; de Bruin, B.; van der Vlugt, J.I.; Reek, J.N.H.; J. Am. Chem. Soc. 2012, 134, 6607−6616.
[link]
94. Synthesis and Reactivity of
Ester-Functionalized 5-Membered RhI-k2-C,O-Chelates and their Relevance in
Rh(cod)-Mediated Carbene Polymerization
Finger, M.; Lutz, M.; Reek, J.N.H.; de Bruin, B.*; Eur. J. Inorg. Chem.
2012, 9, 1437–1444.
[link]
Invited paper. Special Issue
“Organometallic Chemistry”.
93. Ligand Denticity Controls Enantiomeric
Preference in DNA-based Asymmetric Catalysis
Boersma, A.
J.; de Bruin, B.; Feringa, B. L.; Roelfes, G.; Chem. Commun., 2012, 48, 2394–2396.
[link]
92. Redox Non-innocent Ligands –
Versatile New Tools to Control Catalytic Reactions
Lyaskovskyy, V.; de Bruin, B.*, ACS Catalysis, 2012, 2, 270–279.
[link]
Invited
Review.
Top 10 'most
read' papers of the journal in Q1 2012.
91. Rh-Mediated Carbene Polymerization:
From Multistep Catalyst Activation to Alcohol-Mediated Chain-Transfer
Walters, A.
J. C.; Jellema, E. Finger, M.; Aarnoutse, P.; Smits,
J. M. M.; Reek, J. N. H.; de Bruin, B.*, ACS
Catalysis, 2012,
2, 246–260.
[link]
90. Snapshots of a Reversible Metal-Ligand
Two-Electron Transfer Step Involving Compounds Related by Multiple Types of
Isomerism
Tejel, C.; Asensio, L.; Pilar del Río,
M.; de Bruin, B.; López, J. A.; Ciriano, M. A. Eur. J. Inorg.
Chem. 2012, 3, 512–519.
[link]
Special Issue “Cooperative & Redox Non-Innocent Ligands
in Directing Organometallic Reactivity”.
2011
89. Electronic Selectivity Tuning in TiIII-Catalyzed Acetylene Cross-Dimerization
Reactions
Oshovsky, G.V.*; Hessen, B.; Reek, J.N.H.; de Bruin, B.*; Organometallics, 2011,
30, 6067‑6070.
[link]
88. Developing Synthetic Approaches with
Non-Innocent Metalloligands: Easy Access to IrI/Pd0 and IrI/Pd0/IrI cores
Tejel, C.; Asensio, L.; del Río, M.
P.; de Bruin, B.; López, J. A.; Ciriano, M. A. Angew. Chem. Int.
Ed. 2011, 50, 8839–8843.
[link]
87. Mechanism of Cobalt(II)
Porphyrin-Catalyzed C−H Amination with Organic Azides:
Radical Nature and H-Atom Abstraction Ability of the Key Cobalt(III)-Nitrene
Intermediates
Lyaskovskyy, V.; Olivos Suárez, A. I.; Lu, H.;
Jiang, H.; Zhang, X. P.*; de Bruin, B.* J. Am. Chem. Soc. 2011, 133, 12264–12273.
[link]
86. Experimental Evidence for
Cobalt(III)-Carbene Radicals: Key Intermediates in Cobalt(II)-Based Metalloradical Cyclopropanation
Lu,
H.; Dzik, W.I.; Xu, X;. Wojtas, L.; de Bruin, B.*; Zhang, X.P.* J. Am. Chem. Soc. 2011, 133, 8518–8521.
[link]
85. Pincer Ligands with an
All-Phosphorus Donor Set: Subtle Differences between Rhodium and Palladium
Bauer,
R.C.; Gloaguen, Y.; Lutz, M.; Reek, J.N.H.; de Bruin,
B.; van der Vlugt, J.I., Dalton Trans., 2011, 40, 8822–8829.
[link]
84. Cooperative
Double Deprotonation of Bis(2-picolyl)amine Leading to Unexpected Bimetallic
Mixed Valence
(M-I, MI) Rhodium
and Iridium Complexes
Tejel, C.*; del Río, M.P.; Asensio, L.; van den Bruele, F.J.; Ciriano, .A.;Tsichlis i Spithas, N.; Hetterscheid, D.G.H.; de Bruin, B.* Inorg. Chem. 2011, 50,
7524-7534.
[link]
83. The Radical Mechanism
of Cobalt(II) Porphyrin-Catalyzed Olefin
Aziridination and the Importance of Cooperative H-Bonding.
Olivos Suarez, A.I.;
Jiang, H.; Zhang, X.P.*; de Bruin, B.*, Dalton
Trans., 2011, 40, 5697-5705.
[link]
Inside Front Cover.
82.
Open-shell
Organometallic [MII(dbcot)(bis-lutidylamine)]2+ complexes (M = Rh, Ir); Unexpected Base-Assisted Reduction
of the Metal instead of Amine Ligand
Deprotonation.
Dzik, W.I.; Fuente,
L.A., Siegler, M.A.; Spek, A.L.; Reek, J.N.H.; de Bruin, B.*, Organometallics, 2011, 30, 1902-1913.
[link]
81.
The Redox
Non-Innocence of Carbene Ligands: Carbene Radicals in (Catalytic) C‑C
Bond Formation
Dzik, W.I.; Zhang, X.P.; de Bruin,
B.*, Inorg. Chem., 2011, 50, 9896–9903.
[link]
Invited Forum paper. Forum Issue on
‘New Chemistry of Redox Active Ligands’.
80.
The role of b-H elimination
in Rh Mediated Carbene Insertion Polymerization.
Finger, M.;
Reek, J.N.H.; de Bruin, B.*, Organometallics, 2011,
30, 1094-1101.
[link]
79. Carbene Insertion into Transition Metal-Carbon Bonds: New Tool for
Catalytic C–C Bond Formation
Franssen, N.M.G.
Walters, A.J.C.; Reek, J.N.H.; de Bruin, B.*, Catalysis Science & Technology, 2011, 1, 153-165.
[link]
‘Hot Article’. Front Cover.
78.
Binuclear
[(cod)(Cl)Ir(bpi)Ir(cod)]+
for Catalytic Water Oxidation.
Dzik, W.I.; Calvo,
S.E.; Reek, J.N.H.; Lutz, M.; Ciriano, M.A.; Tejel, C.; Hetterscheid, D.G.H.;
de Bruin, B.*; Organometallics, 2011, 30, 372-374 (communication).
[link]
77.
Amino Olefin
Nickel(I) and Nickel(0) Complexes as Dehydrogenation Catalysts for Amine
Boranes.
Vogt,
M.; de Bruin, B.; Berke, H.; Trincado,
M.; Grützmacher, H.; Chemical Science, 2011, 2, 723-727.
[link]
76.
Remote
Supramolecular Control of Catalyst Selectivity in the Hydroformylation of
Alkenes.
Dydio, P.; Dzik, W.I.; Lutz, M. de Bruin, B.; Reek,
J.N.H.; Angew. Chem. Int. Ed., 2011, 50, 396-400.
[link]
Hot Paper. Back cover.
75.
Ligands that
Store & Release Electrons during Catalysis.
Dzik, W.I.;
van der Vlugt, J.I.; Reek, J.N.H.; de Bruin, B.*; Angew. Chem. Int. Ed.,
2011, 50, 3356–3358.
[link]
74.
Pd-Mediated
Carbene Polymerisation: Activity of Palladium(II) versus Low-Valent Palladium.
Franssen,
N.M.G.; Reek, J.N.H.; de Bruin, B.*; Polymer Chemistry,
2011, 2, 422-431.
[link]
Invited paper. Special Issue
Emerging Researchers in Polymer Chemistry.
2010
73.
Preparation,
Characterization and Electronic Structure of Homoleptic Diphosphacyclobutadiene
Complexes
[M(η4-P2C2R2)2]x–
(M = Fe, Co; x = 0, 1).
Wolf, R.; Ehlers, A.W.;
Khusniyarov; M.M. Hartl, F.; de Bruin, B.; Long,
G.J.; Grandjean, F.; Schappacher, F.M.; Pöttgen, R.; Slootweg, J.C.; Lutz, M.; Spek, A.L.; Lammertsma,
K.; Chem. Eur. J. 2010,
16, 14322–14334.
[link]
72.
Rh-mediated
Stereospecific Carbene Polymerization: From Homopolymers to Random and Block
Copolymers.
Jellema, E.; Jongerius, A.L.; Alberda van Ekenstein,
G.; Mookhoek, S.D.; Dingemans,
T.J.; Reingruber, E.M.; Chojnacka, A.; Schoenmakers,
P.J.; Sprenkels, R.; van Eck, E.R.H.; Reek, J.N.H.;
de Bruin, B.*; Macromolecules, 2010, 43, 8892-8903.
[link]
71. ‘Carbene Radicals’ in CoII(por)-Catalyzed Olefin Cyclopropanation.
Dzik, W.I.; Xu, X.; Zhang,
X.P.*; Reek, J.N.H.; de Bruin, B.*; J. Am. Chem. Soc., 2010, 132, 10891-10902.
[link]
70. Multitechnique Approach to Reveal the Mechanism of Copper(II)-Catalyzed Arylation Reactions.
Tromp, M.; van Strijdonck, G.P.F.; van Berkel,
S.S. van den Hoogenband, A.; Feiters, M.C.; de Bruin,
B.; Fiddy, S.G.; van der Eerden, A.M. J.; van
Bokhoven, J.A.; van Leeuwen, P.W.N.M.; Koningsberger, D.C.; Organometallics, 2010, 29,
3085-3097.
[link]
69.
Ureaphosphanes as Hybrid, Anionic or Supramolecular
Bidentate Ligands for Asymmetric Hydrogenation Reactions.
Meeuwissen, J.; Detz, R.J.;
Sandee, A. J.; de Bruin, B.; Siegler, M.A.; Spek, A.L.; Reek, J.N.H.; Eur.
J. Inorg. Chem. 2010, 19,
2992-2997.
[link]
68.
Versatile
New C3-Symmetric Tripodal Tetraphosphine
Ligands; Structural Flexibility to Stabilize CuI
and RhI Species and Tune Their Reactivity.
Wassenaar,
J.; Siegler, M.A.; Spek, A.L.; de Bruin, B.; Reek,
J.N.H.; van der Vlugt, J.I.; Inorg. Chem. 2010, 49, 6495-6508.
[link]
67.
Rhodium-Catalyzed Asymmetric Hydroformylation with Taddol-Based IndolPhos Ligands.
Wassenaar, J.; de Bruin, B.; Reek, J.N.H.; Organometallics, 2010, 29, 2767-2776.
[link]
66.
Ligand
Design in Rh(diene)-Mediated "Carbene" Polymerization; Efficient Synthesis
of High-Mass, Highly Stereoregular, and
Fully Functionalized Carbon-Chain
Polymers.
Jellema, E.; Jongerius, A.L.; Walters, A.J.C.; Smits, J.M.M.; Reek,
J.N.H.; de Bruin, B.*; Organometallics,
2010, 29, 2823-2826.
[link]
65.
Antiferromagnetic
interactions in a distorted cubane-type tetranuclear manganese cluster.
Kampert, E.; Russcher, J.C.; Boukhvalov, D.W.;
Janssen, F.F.B.J.; Smits, J.M.M.; de Gelder, R.; de Bruin, B.; Christianen, P.C.M.; Rowan, A.E.; Katsnelson, M.I.; Maan,
J.C.; Zeitler, U.; J. Phys.: Conf. Ser.,
2010, 200, 022022.
64.
Phosphinoureas: Cooperative Ligands in Rhodium-Catalyzed Hydroformylation? On the Possibility of a
Ligand-Assisted Reductive
Elimination of the Aldehyde.
Meeuwissen, J.; Sandee,
A.J.; de Bruin, B.; Siegler, M.A.; Spek, A.L.; Reek, J.N.H.; Organometallics, 2010, 29, 2413-2421.
[link]
63.
Rhodium(I)
mediated arylation of aldehydes with arylboronic
acids under base and water free conditions: A computational study.
Olivos Suarez, A.I.;
Reek, J.N.H.; de Bruin, B.*; J. Mol. Cat.
A: Chem., 2010, 324, 24-30.
[link]
Invited paper. Special issue on
Computational Catalysis.
62.
C1
polymerisation and related C-C bond forming 'carbene insertion' reactions.
Jellema, E.;
Jongerius, A.L.; Reek, J.N.H.; de Bruin, B.*; Chem. Soc. Rev., 2010, 39, 1706-1723.
[link]
Invited Review.
61.
Carbonyl
Complexes of Rhodium with N-Donor Ligands: Factors Determining the Formation of
Terminal versus Bridging Carbonyls.
Dzik, W.I.;
Creusen, C.; de Gelder, R.; Peters, T.P.J.; Smits, J.M.M.; de Bruin, B.*; Organometallics, 2010, 29, 1629-1641.
[link]
60.
Activation
of H2 by a highly distorted RhII
complex with a new C3-symmetric tripodal tetraphosphine
ligand.
Wassenaar,
J.; de Bruin, B.; Siegler, M.A.; Spek, A.L.; Reek,
J.N.H.; van der Vlugt, J.I.; Chem. Commun., 2010,
46, 1232-1234.
[link]
59.
Highly
enantioselective hydroformylation of dihydrofurans catalyzed
by hybrid phosphine-phosphonite rhodium complexes.
Chikkali, S.H.; Bellini, R.; Berthon-Gelloz,
G.; van der Vlugt, J.I.; de Bruin, B.; Reek, J.N.H.; Chem. Commun., 2010, 46, 1244-1246.
[link]
58.
Rhodium-P,O-bidentate
coordinated ureaphosphine ligands for asymmetric
hydrogenation reactions.
Meeuwissen,
J.; Detz, R.J.; Sandee, A.J.; de Bruin, B.; Reek,
J.N.H.; Dalton Trans, 2010, 39, 1929-1931.
[link]
57. Electromeric Rhodium Radical Complexes.
Puschmann,
F.F.; Harmer, J.; Stein, D.; Ruegger, H.; de Bruin, B.*;
Grützmacher, H.*; Angew. Chem. Int.
Ed., 2010, 49, 385-389.
[link]
Highlighted in Nature Chemistry (Bally, T.;
Nature Chemistry, 2010, 2,
165-166), C2W, and Chimia
(CHIMIA, 2010, 64(4), 266)
56.
P-C
dichotomy: divergent iron(-I)-mediated alkyne and phosphaalkyne
cycloligomerisations.
Wolf, R., Ghavtadze. N., Weber, K., Schnockelborg,
E.M.; de Bruin, B., Ehlers, A.W.; Lammertsma, K.; Dalton Trans., 2010, 39, 1453 - 1456.
[link]
55.
Rhodium(0) Metalloradicals in Binuclear C-H Activation.
Puschmann,
F.F.; Grützmacher, H.*; de Bruin, B.*, J.
Am. Chem. Soc., 2010, 132, 73-75. (communication).
[link]
2009
54.
Ligand-Controlled Magnetic Interactions in Mn4
Clusters.
Kampert, E.; Janssen,
F.F.B.J.; Boukhvalov, D.W.; Russcher,
J.C.; Smits, J.M.M.; de Gelder, R.; de Bruin, B.*; Christianen,
P.C.M.; Zeitler, U.*; Katsnelson, M.I.; Maan, J.C.; Rowan, A.E.* Inorg. Chem., 2009, 48, 11903-11908.
[link]
53.
Ligand
Centred Reactivity of Bis(picolyl)amine Iridium;
Sequential Deprotonation, Oxidation and Oxygenation of a ‘Non-Innocent’ Ligand.
Tejel, C.*; del Río, M.P.; Ciriano,
M.A.; Reijerse, E.J.; Hartl, F.; Záliš, S.; Hetterscheid, D.G.H.; Tsichlis i Spithas,
N.; de Bruin, B.*; Chem. Eur. J, 2009, 15,
11878-11889.
[link]
52. Supramolecular NHC ligands: On the influence of ZnII-templates
on the activity of RhI(cod) complexes in ‘Carbene Polymerization’.
Rubio, M.; Jellema, E.;
Siegler, M.A.; Spek, A.L.; Reek, J.N.H.*; de Bruin, B.*;
Dalton Trans., 2009, 41, 8970-8976.
[link]
Invited Paper. Themed Issue: Metal Catalyzed
Polymerisation
51.
Water Splitting by Cooperative Catalysis.
Hetterscheid,
D. G. H;. van der Vlugt, J. I.; de Bruin, B.; Reek, J. N. H.; Angew. Chem. Int.
Ed., 2009, 48, 8178-8181.
[link]
50.
Hydrogen-Atom Transfer in Reactions of Organic Radicals with [CoII(por)]. (por=Porphyrinato) and in
Subsequent Addition of [Co(H)(por)] to Olefins.
de Bruin, B.*; Dzik, W.I.; Li, S.; Wayland,
B.B.* Chem. Eur. J., 2009, 15, 4312-4320.
[link]
49. Structure and Reactivity of a Unique Y-Shaped
Tricoordinate Bis(silyl)platinum(II)-NHC Complex.
Berthon-Gelloz, G.; de
Bruin, B.; Tinant, B.; Marko, I.E. Angew. Chem. Int. Ed.,
2009, 48, 3161-3164.
[link]
48.
A Phosphorus Analogue of Bis(h4-cyclobutadiene)iron(0).
Wolf, R.; Slootweg,
J.C.; Ehlers, A.W.; Hartl, F.; de Bruin, B.; Lutz, M.; Spek, A.L.; Lammertsma, K.; Angew. Chem. Int. Ed.,
2009, 48, 3104-3107.
[link]
Front
Cover.
47. Sulfonamido-Phosphoramidite Ligands in Cooperative Dinuclear
Hydrogenation Catalysis.
Patureau,
F.W.; de Boer, S.; Kuil, M.; Meeuwissen, J.; Breuil,
Pierre-Alain R.; Siegler, M.A.; Spek, A.L.; Sandee, A.J.; de Bruin, B.; Reek,
J.N.H.; J. Am. Chem. Soc., 2009,
131, 6683-6685.
[link]
46.
Activation of Carbon Monoxide by (Me3tpa)Rh and (Me3tpa)Ir.
Dzik, W.I.; Smits, J.M.M.; Reek, J.N.H.; de
Bruin, B.*; Organometallics, 2009, 28, 1631-1643.
[link]
2008
45. Intervalent bis(m-aziridinato)MII-MI complexes (M = Rh,
Ir): delocalized metallo-radicals
or delocalized aminyl radicals?
Tejel,
C.*; Ciriano, M.; Passarelli, V.; Lopez, J.A.; de
Bruin, B.*; Chem. Eur. J.,
2008, 14, 10985-10998.
[link]
44.
Ligand oxidation of a deprotonated bis(picolyl)amine
IrI(cod) complex.
Tejel,
C.*; Ciriano, M.A.; del Rio, M.P.; Hetterscheid, D.G.H.; Tsichlis i Spithas, N.; Smits, J.M.M; de
Bruin, B.*; Chem. Eur. J.,
2008, 14, 10932-10936
(Communication).
[link]
43. Exchange of Organic Radicals with Organo-Cobalt Complexes Formed in the Living Radical Polymerization of Vinyl
Acetate.
Li, S.; Peng, C.-H.; Fryd, M.; Wayland, B.B.*; de Bruin, B.*; J. Am. Chem. Soc., 2008, 130,
13373-13381.
[link]
42. Selective
C-C Coupling of ‘Ir(ethene)’ and ‘Ir(Carbenoid)’
Radicals.
Dzik,
W.I; Reek, J.N; de Bruin, B.*, Chem. Eur. J., 2008,
14, 7594-7599.
[link]
41. Deprotonation
induced ligand-to-metal electron transfer: Synthesis of a mixed-valence
Rh(-I,I) dinuclear compound and its reaction with
dioxygen.
Tejel, C.*; Ciriano;
M.A. del Río; M.P. van den Bruele, F.J.; Hetterscheid, D.G.H.;
Tsichlis i Spithas, N.; de Bruin, B.*; J. Am. Chem. Soc., 2008, 130, 5844-5845.
[link]
40. Carbon-Carbon Bond Activation of TEMPO by
a RhII Metallo-Radical: A Combined Experimental
and Theoretical Study.
Chan, K.-S; Li, X.Z;
Dzik, W.I; de Bruin, B.*; J. Am. Chem. Soc, 2008, 130, 2051-2061.
[link]
2007
39. Rh
Mediated Polymerization of Carbenes: Mechanism and Stereoregulation.
Jellema, E.; Budzelaar, P.H.M.;
Reek, J.N.H.; de Bruin, B.*; J. Am. Chem. Soc., 2007, 129, 11631-11641.
[link]
37. Spin density distribution in mononuclear
Rh(0) complexes: A combined experimental and DFT study.
de Bruin,
B.*; Russcher, J.C.; Grützmacher, H.*; J. Organomet. Chem. 2007, 692, 3167-3173.
[link]
Invited paper (Special Issue
about “One-electron Reactivity in Organometallic Chemistry“).
36. Unusual Stereochemistry in
complexes of the form [RhH(CO)2(PiPr3)].
Cheliatsidou, P.; White, D.F.S.; de
Bruin, B.; Reek, J.N.H.; Cole-Hamilton, D.J.; Organometallics, 2007, 26, 3265 - 3268.
[link]
35. Hydrogen-Atom Transfer in Open-Shell
Organometallic Chemistry: The Reactivity of RhII(cod)
and IrII(cod) Radicals.
Hetterscheid, D.G.H.; Klop, M.; Kicken, R.J.N.A.M; Smits, J.M.M.; Reijerse,
E.J.; de Bruin, B.*; Chem. Eur. J., 2007, 13, 3386-3405.
[link]
34. Paramagnetic (alkene)Rh and (alkene)Ir
complexes: metal or ligand radicals?
de Bruin,
B.*; Hetterscheid, D.G.H.; Eur. J. Inorg. Chem.,
2007, 2, 211-230.
[link]
Invited
review.
2006
33. Rhodium-Mediated Stereoselective Polymerization of
“Carbenes”.
Hetterscheid,
D.G.H.; Hendriksen, C. Dzik, W.I.; Smits, J.M.M.; van Eck, E.R.H.; Rowan, A.E.;
Busico, V.; Vacatello, M.; Van Axel Castelli, V.;
Segre, A.; Jellema, E.; Bloemberg, T.G.; de Bruin,
B.*; J.
Am. Chem. Soc., 2006, 128,
9746-9752.
[link]
Highlighted
in Angewandte Chemie (A.F. Noels, Angew. Chem. Int. Ed. 2007, 46, 1208 – 1210.)
Highligted in SynFacts: DOI: 10.1055/s-2006-949358
32.
Dynamic combinatorial chemistry: the unexpected choice of receptors by
guest molecules.
de Bruin, B.; Hauwert, P.; Reek, J. N. H.; Angew. Chem.
Int. Ed., 2006, 45, 2660-2663.
[link]
31. Gas-Phase
Reactivity of an Iridium(I) Complex with Dioxygen –Comparison to Solution Phase
Reactivity.
Thewissen, S.; Plattner, D.A.; de
Bruin, B.; Int. J. Mass Spec., 2006,
249/250, 446-450.
[link]
30.
Open-Shell Rhodium and Iridium
Species in (Catalytic) Oxygenation Reactions.
Hetterscheid, D.G.H.; de Bruin, B.*, J. Mol. Catal. A,
Chemical, 2006, 251, 291-296.
[link]
2005-2002 (Assistant
professor RU Nijmegen)
29. Formation of a paramagnetic
Al complex and extrusion of Fe during the reaction of (diiminepyridine)Fe
with AlMe3 (R= Me,Et).
Scott, J.; Gambarotta,
S.; Korobkov, I.; Knijnenburg,
Q.; de Bruin, B.; Budzelaar, P.H.M.; J. Am. Chem.
Soc., 2005, 127,17204-17206.
[link]
28. Instability
of square planar N3-ligand Iridium(I) ethene complexes.
Thewissen, S.; Reijnders, M.D.M.;
Smits, J.M.M.; de Bruin, B.*; Organometallics, 2005, 24, 5964-5972.
[link]
27. IrII(ethene):
Metal or Carbon Radical? Part II: Oxygenation via Iridium or Direct Oxygenation
at Ethene?
Hetterscheid,
D.G.H.; Bens, M.; de Bruin, B.*; Dalton Trans., 2005, 5, 979-984.
[link]
26. Olefin hydrogenation using diimine pyridine complexes of Co and Rh.
Knijnenburg, Q.; Horton,A.D.;
van der Heijden, H. Kooistra, T.M.; Hetterscheid,
D.G.H.; Smits, J.M.M.; de Bruin, B.; Budzelaar,
P.H.M; Gal, A.W.; J. Mol. Catal. A, Chemical, 2005, 232, 151-159.
[link]
25. IrII(ethene); Metal or Carbon Radical?
Hetterscheid, D.G.H.; Kaiser, J.; Reijerse,
E.; Peters, T.P.J.; Thewissen, S.; Blok, A.N.J.; Smits, J.M.M.; de Gelder, R.;
de Bruin, B.*; J. Am. Chem. Soc., 2005, 127, 1895-1905.
[link]
24. Chloride-triggered
disproportionation of a mononuclear RhII(nbd) species to RhI(nbd) and RhIII(h1-norbornenyl) complexes: Possibilities for
Wacker type mono-oxygenation of norbornadiene to norbornenone.
Hetterscheid, D.G.H.; Smits, J.M.M.; de Bruin, B.*; Organometallics, 2004, 23, 4236-4246.
[link]
23. Functional
models for rhodium-mediated olefin
oxygenation.
de Bruin, B.*; Budzelaar,
P.H.M.; Gal, A.W.; Angew. Chem. Int. Ed., 2004, 43,
4142-4157.
[link]
Invited Review.
22. Etching
AlAs with HF for epitaxial lift-off applications.
Voncken, M.M.A.J.; Schermer, J.J.;
van Niftrik A.T.J.; Bauhuis, G.J.; Mulder, P.;
Larsen, P.K.; Peters, T.P.J.; de Bruin, B.; Klaassen, A.; Kelly, J.J.; J. Electrochem. Soc., 2004, 151, G347-G352.
[link]
21. Disproportionation of RhII(cod) to RhI(cod)
and RhIII(cycloocta-2,5-dien-1-yl):
Hydrogen Atom Transfer vs Electron and Proton Transfer.
Hetterscheid, D.G.H.; de Bruin, B.*; Smits, J.M.M.; Gal,
A.W.; Organometallics, 2003, 22,
3022-3024.
[link]
20. Cobalt
chloride complexes of N3 and N4 donor ligands.
Kooistra T.M.; Hekking K.F.W.; Knijnenburg Q; de Bruin B; Budzelaar
P.H.M.; de Gelder R; Smits J.M.M.; Gal A.W.; Eur. J. Inorg. Chem., 2003,
4, 648-655.
[link]
19. Formation of ethylene bridged dinuclear IrIII species via coupling of IrII and IrII(ethene).
de Bruin, B.*; Thewissen,
S.; Yuen, T.-W.; Peters, T.P.J.; Smits, J.M.M.; Gal, A.W.; Organometallics, 2002, 21, 4312-4314.
[link]
18. Dioxygenation
of sterically hindered RhI- and IrI-ethene complexes to peroxo-
and peroxo-ethene complexes.
de Bruin, B.*; Peters, T.P.J.;
Wilting, J.B.M.; Thewissen, S.; Smits, J.M.M.; Gal,
A.W.; Eur. J. Inorg. Chem., 2002,
10, 2671-2680.
[link]
17. Amido-bridged
dinuclear rhodium(I) complexes by deprotonation of
mononuclear rhodium(I) amine complexes.
de Bruin, B.; Peters, T.P.J.; Suos,
N.F.A.; de Gelder, R.; Smits, J.M.M.; Gal, A.W.; Inorg. Chim. Acta, 2002,
337, 154-162.
[link]
16. Dioxygen
activation by an unprecedented mononuclear IrII-ethene
complex.
de Bruin, B.*; Peters, T.P.J.; Thewissen, S.; Blok,
A.N.J.; Wilting, J.B.M.; de Gelder, R.; Smits,
J.M.M.; Gal, A.W.; Angew. Chem. Int. Ed., 2002, 41,
2135-2138.
[link]
15. Spontaneous disproportionation of rhodium(I) bisoxazolinates to rhodium(II).
Willems,
S.T.H.; Russcher, J.C.; Budzelaar,
P.H.M.; de Bruin, B.; de Gelder, R.; Smits, J.M.M.; Gal, A.W.; Chem. Commun.,
2002, 148-149.
[link]
14. New routes toward metallated
methanofullerene terdentate
bisaminoaryl ligands.
Meijer, M.D.; Klink, G.P.M. van; de
Bruin, B.; van Koten, G.; Inorg. Chim.
Acta, 2002, 327, 31-40.
[link]
2001-1993 (Undergraduate, PhD
and postdoc research)
13. Metal-to-ligand electron transfer in diiminopyridine
complexes of Mn-Zn - a theoretical study.
Budzelaar, P.H.M.; de Bruin, B.; Gal, A.W.; Wieghardt, K.E.; van Lenthe, J.H.; Inorg.
Chem.,
2001, 40, 4649-4655.
[link]
12. Synthesis, Aggregation, and Binding Behaviour of Synthetic Amphiphilic Receptors.
Schenning,
A.P.H.J.; Escuder, B.; van Nunen, J.L.M.; de Bruin,
B.; Loewik, D.W.P.M.; Rowan, A.E.; van der Gaast,
S.J.; Feiters, M.C.; Nolte, R.J.M.; J. Org. Chem.,
2001, 66, 1538-1547.
[link]
11. Enhanced Reactivity of 2‑Rhodaoxetanes Through a Labile
Acetonitrile Ligand.
de Bruin, B.;
Verhagen, J.A.W.; Schouten, C.H.J.; Gal, A.W.; Feichtinger, D.; Plattner, D.A.;
Chem. Eur. J., 2001, 7, 416-422.
[link]
10. Molecular and Electronic Structures of
Bis(pyridine-2,6-diimine)metal Complexes [ML2](PF6)n
(n = 0, 1, 2, 3; M = Mn, Fe, Co, Ni, Cu, Zn).
de
Bruin, B.; Bill, E.; Bothe, E.; Weyhermueller, T.; Wieghardt, K.; Inorg. Chem., 2000, 39,
2936-2947.
[link]
9. 2-Rhodaoxetanes: Their Formation by
Oxidation of [RhI(ethene)]+ and
Their Reactivity upon Protonation.
de Bruin, B.;
Boerakker, M.J.; Verhagen, J.A.W.; de Gelder, R.; Smits, J.M.M.; Gal, A.W.; Chem. Eur. J., 2000,
6, 298-312.
[link]
8. Selective Oxidation of [RhI(cod)]+ by H2O2
and O2.
de
Bruin, B.; Brands, J.A.; Donners, J.J.J.M., Donners, M.P.J., de Gelder, R.;
Smits, J.M.M.; Gal, A.W.; Spek, A.L.; Chem. Eur. J., 1999, 5,
2921-2936.
[link]
7. Diversity in Complexation of [RhI(cod)]+ and [IrI(cod)]+
by Pyridine-Amine-Pyrrole Ligands.
de
Bruin, B.; Kicken, R.J.N.A.M.; Suos, N.F.A., Donners,
M.P.J., den Reijer, C.J.; Sandee, A.J.; de Gelder, R.; Smits, J.M.M.; Gal,
A.W.; Spek, A.L.; Eur. J. Inorg. Chem., 1999, 1581-1592.
[link]
6. Amidation of
[RhI(ethene)]+ by H2O2/Acetonitrile
via a 2-Rhodaoxetane.
de Bruin, B.; Boerakker,
M.J.; de Gelder, R.; Smits, J.M.M.; Gal, A.W.; Angew.
Chem. Int. Ed., 1999,
38, 219 - 222; Angew.
Chem., 1999, 111, 118-121.
[link]
5. Mono- and Di-nuclear Carbonyl Complexes
of (1,4,7-Trimethyl-1,4,7-triazacyclononane)rhodium(I): Facile Migration of a
C(O)OMe Ligand at a Dinuclear
Rh(m-CO)2Rh Core.
de
Bruin, B.; Donners, J.J.J.M.; de Gelder, R.; Smits, J.M.M.; Gal, A.W.; Eur.
J. Inorg. Chem., 1998, 3, 401-406.
[link]
4. Oxidation of RhI(olefin)
Fragments to 2‑Rhodaoxetanes.
de
Bruin, B.; Boerakker, M.J.; Donners, J.J.J.M.; Christiaans, B.E.C.; Schlebos,
P.P.J.; de Gelder, R.; Smits, J.M.M.;
Spek, A.L.; Gal, A.W.;
Angew. Chem. Int. Ed. Engl., 1997,
36, 2063 - 2067; Angew. Chem., 1997,
109, 2153-2157.
[link]
3. Strong Binding of Paraquat and
Polymeric Paraquat Derivatives by Basket-Shaped Hosts.
Schenning,
A.P.H.J.; de Bruin, B.; Rowan, A.E.; Kooiman, H.; Spek, A.L.; Nolte, R.J.M.; Angew. Chem. Int. Ed. Engl., 1995, 34,
2132 - 2134; Angew. Chem.
1995, 107, 2288-2289.
[link]
2. Molecular golfballs:
Vesicles from bowl-shaped host molecules.
Schenning, A.P.H.J.; de Bruin, B.; Feiters,
M.C.; Nolte, R.J.M.; Angew.
Chem. Int. Ed. Engl. 1994, 33,
1662-1663; Angew. Chem., 1994,
106, 1741-1742.
[link]
1. Bridging CH2 addition to the
disulfur ligands of an iron-sulfur cluster compound.
Berg, W. van den;
Linden, J.G.M. van der; Riessen, B.A. van; de Bruin,
B.; Bosman, W.P.; Smits, J.M.M.; Beurskens, P.T.; Inorg. Chem., 1993,
32, 3637-3639.
[link]
